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Synthesis and characterization of poly [N-acryl-N-sulfonic acid-N yL-2-substituted-4-oxo-thiazolidine] maleic and succinic di imide
Other Title(s)
تحضير و تشخيص بولي] N-أكريل-N-حامض السمفونيك-N- يل-2-معوض-4-أوكسو ثايازوليدين [سكسنك أو ماليك داي إيمايد
Joint Authors
al-Tamimi, Intisar Uayd Prisse
Abd al-Husayn, Haydar Muhammad Amin
Source
Issue
Vol. 55, Issue 3A (30 Sep. 2014), pp.912-931, 20 p.
Publisher
University of Baghdad College of Science
Publication Date
2014-09-30
Country of Publication
Iraq
No. of Pages
20
Main Subjects
Abstract EN
In the present investigation, new polymers of Poly [ N-acryl - N - sulfonic acid - N\ yL-2- substitute-4-oxo - thiazolidine ] Maleic and Succinic diimide were synthesized by seven steps; first step includes esterification of different cyclic anhydride, using one mole of absolute methanol in the presence few drops of conc.
H2SO4, yielded mono group ester [I] , which was reaction with thionyl chloride to give ester acid chloride [II] .Then reacted with sulfanilic acid to product compound [III] , which was condensation with hydrazine hydrate to give acid hydrazide [IV] .
The new different Schiff bases [V-VIII] were synthesized by reaction of acid hydraizide with different (aliphatic and aromatic) aldehyedes and ketones in the presence of glacial acetic acid.
Thiazolidine-4-one derivatives [IX-XII] have been obtained from the addition of 2-mercapto acetic acid to Schiff bases and the final step was added poly acryloyl chloride to product polymers [XIII-XVI] .
There chemical structures have been confirmed by melting points , FTIR,1HNMR and 13C-NMR (some of them).
All the synthesized polymers were characterized by FT– IR spectra, softening points and TGA,DTG (some of them).
American Psychological Association (APA)
al-Tamimi, Intisar Uayd Prisse& Abd al-Husayn, Haydar Muhammad Amin. 2014. Synthesis and characterization of poly [N-acryl-N-sulfonic acid-N yL-2-substituted-4-oxo-thiazolidine] maleic and succinic di imide. Iraqi Journal of Science،Vol. 55, no. 3A, pp.912-931.
https://search.emarefa.net/detail/BIM-394242
Modern Language Association (MLA)
al-Tamimi, Intisar Uayd Prisse& Abd al-Husayn, Haydar Muhammad Amin. Synthesis and characterization of poly [N-acryl-N-sulfonic acid-N yL-2-substituted-4-oxo-thiazolidine] maleic and succinic di imide. Iraqi Journal of Science Vol. 55, no. 3A (2014), pp.912-931.
https://search.emarefa.net/detail/BIM-394242
American Medical Association (AMA)
al-Tamimi, Intisar Uayd Prisse& Abd al-Husayn, Haydar Muhammad Amin. Synthesis and characterization of poly [N-acryl-N-sulfonic acid-N yL-2-substituted-4-oxo-thiazolidine] maleic and succinic di imide. Iraqi Journal of Science. 2014. Vol. 55, no. 3A, pp.912-931.
https://search.emarefa.net/detail/BIM-394242
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 931
Record ID
BIM-394242