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Synthesis of dimethylvinylsilyloxyalkenes from aldehydes and ketones
Joint Authors
Abbas, K. A.
Fataftah, Zakariyya A.
Source
Mu'tah Journal for Research and Studies : Natural and Applied Sciences Series
Issue
Vol. 10, Issue 1 (31 Mar. 1995), pp.11-24, 14 p.
Publisher
Mutah University Deanship of Academic Research
Publication Date
1995-03-31
Country of Publication
Jordan
No. of Pages
14
Main Subjects
Abstract EN
Chlorodimethylvinylsilane is reacted with an equivalent amount of ketone or aldehyde enolates.
obtained from deprotonation of 3-pentanone, 3,3-dimethyl-2-butanone.
acetophenone, propiophenone, cyclopentanone, cyclohexanone.
cyclohep-tanone, pentanal, hexanal and heptanal.
to give dimethylvinylsilyloxyalkenes in good yields.
Triethylamine as well as lithium diisopropylamide (LDA) are used in deprotonation of aldehydes and ketones.
Acetophenone and 3,3-dimethyl-2-bulanone give low yields with triethylamine and the aldehydes give poor yields with LDA.
The acid- and base -catalyzed rate of hydrolysis of 1 was examined.
All products have been characterized on the basis of their NMR, IR and elemental analysis data.
American Psychological Association (APA)
Fataftah, Zakariyya A.& Abbas, K. A.. 1995. Synthesis of dimethylvinylsilyloxyalkenes from aldehydes and ketones. Mu'tah Journal for Research and Studies : Natural and Applied Sciences Series،Vol. 10, no. 1, pp.11-24.
https://search.emarefa.net/detail/BIM-396169
Modern Language Association (MLA)
Fataftah, Zakariyya A.& Abbas, K. A.. Synthesis of dimethylvinylsilyloxyalkenes from aldehydes and ketones. Mu'tah Journal for Research and Studies : Natural and Applied Sciences Series Vol. 10, no. 1 (Mar. 1995), pp.11-24.
https://search.emarefa.net/detail/BIM-396169
American Medical Association (AMA)
Fataftah, Zakariyya A.& Abbas, K. A.. Synthesis of dimethylvinylsilyloxyalkenes from aldehydes and ketones. Mu'tah Journal for Research and Studies : Natural and Applied Sciences Series. 1995. Vol. 10, no. 1, pp.11-24.
https://search.emarefa.net/detail/BIM-396169
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 24
Record ID
BIM-396169