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Synthesis and characterization of triphenyltin (TV) complexes with some Schiff -base derivatives
Joint Authors
al-Allaf, Talal Ahmad Khalil
al-Shama, Manal A.
Source
Mu'tah Journal for Research and Studies : Natural and Applied Sciences Series
Issue
Vol. 11, Issue 6 (31 Dec. 1996), pp.105-118, 14 p.
Publisher
Mutah University Deanship of Academic Research
Publication Date
1996-12-31
Country of Publication
Jordan
No. of Pages
14
Main Subjects
Abstract EN
Triphenyltin (IV) complexes, PhjStiX.L, where X « OH, Cl,N^NO^ and L * Schiff-base derived from substituted or non-substituted 2-or 3- aminopyridine and 2-hydroxy (or 2-methoxy) benzaldehyde, have been synthesised and characterized physicochemically and spectroscopically.
The Schiff-base seems to coordinate with tin metal in a monodentate fashion via the most reactive bonding site; the central imine (azomethine) nitrogen, giving complexes with tin of penta - coordination number.
With few exceptions, all the triphenyltin chloride and the nitrate complexes showed almost 1:1 conductivity in both solvents EtOH and DMF indicating the ionic structure [Ph3Sn.L]+ Xwhereas all the hydroxide and the azide complexes showed almost non * conductive species, indicating the non - ionic structure [ Ph3SnX.L] in solution.
Explanation for such results have been given and discussed..
American Psychological Association (APA)
al-Allaf, Talal Ahmad Khalil& al-Shama, Manal A.. 1996. Synthesis and characterization of triphenyltin (TV) complexes with some Schiff -base derivatives. Mu'tah Journal for Research and Studies : Natural and Applied Sciences Series،Vol. 11, no. 6, pp.105-118.
https://search.emarefa.net/detail/BIM-396637
Modern Language Association (MLA)
al-Allaf, Talal Ahmad Khalil& al-Shama, Manal A.. Synthesis and characterization of triphenyltin (TV) complexes with some Schiff -base derivatives. Mu'tah Journal for Research and Studies : Natural and Applied Sciences Series Vol. 11, no. 6 (Dec. 1996), pp.105-118.
https://search.emarefa.net/detail/BIM-396637
American Medical Association (AMA)
al-Allaf, Talal Ahmad Khalil& al-Shama, Manal A.. Synthesis and characterization of triphenyltin (TV) complexes with some Schiff -base derivatives. Mu'tah Journal for Research and Studies : Natural and Applied Sciences Series. 1996. Vol. 11, no. 6, pp.105-118.
https://search.emarefa.net/detail/BIM-396637
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 116-118
Record ID
BIM-396637