Fluxional behaviour of phosphine complexes of tri carbon yl-ri5 cyclopentadienylhydridotungsten 1
Source
Mu'tah Journal for Research and Studies : Natural and Applied Sciences Series
Issue
Vol. 9, Issue 2 (31 Jul. 1994), pp.39-56, 18 p.
Publisher
Mutah University Deanship of Academic Research
Publication Date
1994-07-31
Country of Publication
Jordan
No. of Pages
18
Main Subjects
Abstract EN
Complexes of the general formula [ W ( rj5-C5Hs ) ( CO ) nLH ], n = 2, L=PMe2Ph, PEt2Ph, PMePh2, PMunPh2, PBu"3, P(CH2Ph)3, P(OPh) and n = 1, L = Ph2PCH2CH2PPh2, have been isolated and chaiacterized by IR, NMR (1H, 13C, 3lp) and mass spectroscopy.
Interconversion of ds and trans isomers has been studied by variable temperature JH NMR measurements and values of AH- and AG~ associated with isomerisation have been calculated.
The results are compared with those from analogous molybdenum complexes made previously by others.
American Psychological Association (APA)
al-Ahaf, Talal A. K.& Smith, John D.. 1994. Fluxional behaviour of phosphine complexes of tri carbon yl-ri5 cyclopentadienylhydridotungsten 1. Mu'tah Journal for Research and Studies : Natural and Applied Sciences Series،Vol. 9, no. 2, pp.39-56.
https://search.emarefa.net/detail/BIM-397091
Modern Language Association (MLA)
al-Ahaf, Talal A. K.& Smith, John D.. Fluxional behaviour of phosphine complexes of tri carbon yl-ri5 cyclopentadienylhydridotungsten 1. Mu'tah Journal for Research and Studies : Natural and Applied Sciences Series Vol. 9, no. 2 (Jul. 1994), pp.39-56.
https://search.emarefa.net/detail/BIM-397091
American Medical Association (AMA)
al-Ahaf, Talal A. K.& Smith, John D.. Fluxional behaviour of phosphine complexes of tri carbon yl-ri5 cyclopentadienylhydridotungsten 1. Mu'tah Journal for Research and Studies : Natural and Applied Sciences Series. 1994. Vol. 9, no. 2, pp.39-56.
https://search.emarefa.net/detail/BIM-397091
Data Type
Journal Articles
Language
English
Notes
Includes appendices : p. 49-54
Record ID
BIM-397091
