Cyclic voltammetric studies on s-bonded iron thiocarboxylates in acetonitrile
Source
Mu'tah Journal for Research and Studies : Natural and Applied Sciences Series
Issue
Vol. 9, Issue 2 (31 Jul. 1994), pp.81-93, 13 p.
Publisher
Mutah University Deanship of Academic Research
Publication Date
1994-07-31
Country of Publication
Jordan
No. of Pages
13
Main Subjects
Abstract EN
Following a recent procedure, a series of dicarbonylcyclopentadienyliron S-bonded thiocarboxylates were prepared and studied.
The effect of different substitution patterns, in the cyclopentadienyl ring and in the thiocarboxylate group with aliphatic and aromatic substrates, on the electrochemical behaviour is analyzed and discussed.
The cyclic voltammetric measurements were performed in acetonitrile and the origins of anodic oxidation and cathodic reduction peaks are assigned to specific functional groups and molecular sites.
Electro oxidation is found to take place at the iron and the cyclopentadienyl ring, while reduction occurs at the aromatic-thiocarboxylate and the cyclopentadienly ring.
Dedicated to the momory of Dr.
Mahmoud El-Hinnaw Author to whom correspondence should be addressed.
American Psychological Association (APA)
Tabba, Hani D.& Barqawi, Khalid R.. 1994. Cyclic voltammetric studies on s-bonded iron thiocarboxylates in acetonitrile. Mu'tah Journal for Research and Studies : Natural and Applied Sciences Series،Vol. 9, no. 2, pp.81-93.
https://search.emarefa.net/detail/BIM-397126
Modern Language Association (MLA)
Tabba, Hani D.& Barqawi, Khalid R.. Cyclic voltammetric studies on s-bonded iron thiocarboxylates in acetonitrile. Mu'tah Journal for Research and Studies : Natural and Applied Sciences Series Vol. 9, no. 2 (Jul. 1994), pp.81-93.
https://search.emarefa.net/detail/BIM-397126
American Medical Association (AMA)
Tabba, Hani D.& Barqawi, Khalid R.. Cyclic voltammetric studies on s-bonded iron thiocarboxylates in acetonitrile. Mu'tah Journal for Research and Studies : Natural and Applied Sciences Series. 1994. Vol. 9, no. 2, pp.81-93.
https://search.emarefa.net/detail/BIM-397126
Data Type
Journal Articles
Language
English
Notes
Includes appendices : p. 89-91
Record ID
BIM-397126