Isomerization Of 1-hexene by Pd (II) in acetone
Joint Authors
Usfur, Hasan M.
al-Sawi, Muhammad Izzat Khalil
Source
Mu’tah Journal for Research and Studies
Issue
Vol. 3, Issue 2 (31 Dec. 1988), pp.25-31, 7 p.
Publisher
Publication Date
1988-12-31
Country of Publication
Jordan
No. of Pages
7
Main Subjects
Topics
Abstract AR
تظهر دراسة تفاعل 1-هكسين (10-1 مولر) مع رباعي كلوروبلدات (Ⅱ) الصوديوم (Na2 PdCl4)، 4 × 10-4 مولر في الأستون النقي إن هكسين-Pd (Ⅱ) يتكون أولا ثم يحدث أزمة للهكسين في المتراكب و ينفصل 2-هكسين حر.
في هذا التفاعل لا يتكون الدايمر [PdCl2 (hexane)] عند وجود الأستون كمذيب و لكن أمكن تكوين و فصل هذا المتراكب بالتفاعل المباشر بين 1-هكسين و Na2 PdCl4 عند درجة -5° م.
و سرعة هذا التفاعل (K1) عندما يكون المذيب هو الأستون : 2.06 × 10-1 مولار-1.
ثا-1، و ثابت الاتزان (K)~75.
Abstract EN
An investigation of the reaction of 1—hexene (lxlO-1 M) with Na2PdCl4(4xlG"' M) in pure acetone showed that Pd(II)—hexene complex is formed first, then an isomerization of the coordinated 1-hexene to free 2-hexene occurs after that.
The dimer [PdCl2(hexene)]2 is not formed in acetone, but it is formed and can be isolated by the direct reaction of 1-hexene with Na2PdCl4 at-5°C.
The rate constant of the reaction in acetone (k j) was found to be 2.06 × 10-1 M-1 S-1 and the equilibrium constant (K) was ~75.
American Psychological Association (APA)
Usfur, Hasan M.& al-Sawi, Muhammad Izzat Khalil. 1988. Isomerization Of 1-hexene by Pd (II) in acetone. Mu’tah Journal for Research and Studies،Vol. 3, no. 2, pp.25-31.
https://search.emarefa.net/detail/BIM-401278
Modern Language Association (MLA)
Usfur, Hasan M.& al-Sawi, Muhammad Izzat Khalil. Isomerization Of 1-hexene by Pd (II) in acetone. Mu’tah Journal for Research and Studies Vol. 3, no. 2 (Dec. 1988), pp.25-31.
https://search.emarefa.net/detail/BIM-401278
American Medical Association (AMA)
Usfur, Hasan M.& al-Sawi, Muhammad Izzat Khalil. Isomerization Of 1-hexene by Pd (II) in acetone. Mu’tah Journal for Research and Studies. 1988. Vol. 3, no. 2, pp.25-31.
https://search.emarefa.net/detail/BIM-401278
Data Type
Journal Articles
Language
English
Notes
Text in English ; abstracts in English and Arabic.
Record ID
BIM-401278
