Synthesis, characterization and biological study of Cr (III), Mn (II), Co (II), Ni (II), Cu (II) and Zn (II) complexes with a new tetradentate Schiff base ligand
Joint Authors
al-Hasani, Rihab Abd al-Mahdi
Muhammad, Sinan Midhat
Rashid, Inam Majid
Source
Iraqi National Journal of Chemistry
Issue
Vol. 2011, Issue 43 (31 Aug. 2011), pp.392-402, 11 p.
Publisher
University of Babylon College of Sciences
Publication Date
2011-08-31
Country of Publication
Iraq
No. of Pages
11
Main Subjects
Abstract AR
يتضمن هذا البحث تحضير ليكاند قاعدة شف الجديدة 3,3- (benzene-1, 4-diyldinitrilo) bis (1, 3-dihydro-2H-indol-2-one) (L) جرى تشخيص (L) بطرائق تحليل طيف الأشعة تحت الحمراء (FT-IR) و طيف الأشعة فوق البنفسجية المرئية و التحليل الدقيق للعناصر (C.
H.
N).
و تم استخدام (L) كاليكاند في تحضير معقدات الأيونات الفلزية : الكروم (III) و المنغنيز (II) و الكوبلت (II) و النيكل (II) و النحاس (II) و الخارصين (II).
عزلت المعقدات الجديدة و تم تشخيصها باستخدام طيف الأشعة الحمراء و طيف الأشعة فوق البنفسجية المرئية و تقنية التحليل الدقيق للعناصر (C.
H.
N) و تقنية الإمتصاص الذري اللهيبي للعناصر غضافة إلى قياسات الحساسية المغناطيسية و التوصيلية الكهربائية.
وتقنية التحليل الدقيق للعناصر (L) و معقداتها و باستخدام تراكيز مختلفة ضد البكتريا (E.
coli) و (Bacillussubtilis)، كما و تم إجراء التقويم الحيوي للمركبات ضد الفطريات باستخدام (A.
niger) و (P.
chrysogenum).
Abstract EN
At this paper we describe the synthesis of new Schiff Base (L) : 3,3`-(benzene-1,4-diyldinitrilo) bis (1,3-dihydro-2H-indol-2-one).
The product (L) was characterized by (FT-IR), (UV-Vis) spectroscopy and elemental analysis (C.
H.
N).
(L) has been used as aligand to prepare a number of metal complexes with Cr (III), Mn (II), Co (II), Ni (II), Cu (II) and Zn (II).
The prepared complexes were isolated and characterized by (FT-IR) and (UV-Vis) spectroscopy, elemental analysis (C.
H.
N) flame atomic absorption technique, as well as magnetic susceptibility and conductivity measurement.
The Schiff base (L) and its complexes, with different concentration, have been screened for their (In-Vitro) antibacterial on (E.
coli) and (Bacillusubtilis) and antifungal (A.
niger) and (P.
chrysogenum) activities by using different concentration.
American Psychological Association (APA)
al-Hasani, Rihab Abd al-Mahdi& Muhammad, Sinan Midhat& Rashid, Inam Majid. 2011. Synthesis, characterization and biological study of Cr (III), Mn (II), Co (II), Ni (II), Cu (II) and Zn (II) complexes with a new tetradentate Schiff base ligand. Iraqi National Journal of Chemistry،Vol. 2011, no. 43, pp.392-402.
https://search.emarefa.net/detail/BIM-406423
Modern Language Association (MLA)
al-Hasani, Rihab Abd al-Mahdi…[et al.]. Synthesis, characterization and biological study of Cr (III), Mn (II), Co (II), Ni (II), Cu (II) and Zn (II) complexes with a new tetradentate Schiff base ligand. Iraqi National Journal of Chemistry No. 43 (2011), pp.392-402.
https://search.emarefa.net/detail/BIM-406423
American Medical Association (AMA)
al-Hasani, Rihab Abd al-Mahdi& Muhammad, Sinan Midhat& Rashid, Inam Majid. Synthesis, characterization and biological study of Cr (III), Mn (II), Co (II), Ni (II), Cu (II) and Zn (II) complexes with a new tetradentate Schiff base ligand. Iraqi National Journal of Chemistry. 2011. Vol. 2011, no. 43, pp.392-402.
https://search.emarefa.net/detail/BIM-406423
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 400-402
Record ID
BIM-406423