Mixed ligand complexes of quinoline-2-carboxylic acid and 4, 4 -dimethyl-2, 2 -bipyridyl with V (IV), Cr (III), Rh (III), Cd (II) and Pt (IV)
Other Title(s)
معقدات الليكندات المختلطة (كوينولين-2-حامض الكاربوكسيلي و 4,4-داي مثيل 2,2 باي برديال) مع فناديوم (IV)، كروم (III)، روديوم (III)، كادميوم (II) و البلاتين (IV)
Joint Authors
Ilyas, Mahasin Faysal Ahmad
Umran, Sahar Ismail
Source
Issue
Vol. 11, Issue 3 (30 Sep. 2014), pp.1180-1191, 12 p.
Publisher
University of Baghdad College of Science for Women
Publication Date
2014-09-30
Country of Publication
Iraq
No. of Pages
12
Main Subjects
Topics
Abstract AR
تم تحضير معقدات جديدة من مفاعلة كوينولين-2-حامض الكربوكسيلي و 4,4`-داي مثيل، 2,2`-باي بريديال مع ايونات الفلزات : فناديوم(IV)، كروم(III), روديوم(III)، كادميوم (II) و البلاتين (IV).تم عزل و تشخيص المركبات المحضرة بالطرق الطيفية و الفيزيائية كطيف الأشعة تحت الحمراء و الأشعة فوق البنفسجية المرئية و التحليل الدقيق للعناصر و تعيين نسبة الفلز و التحليل الحراري بالإضافة الى القياسيات الحساسية المغناطيسية و التوصيلية.
معظم المعقدات المحضرة مونمرية و ذات شكل هندسي ثماني السطوح ماعدا معقدات الفناديويوم مربع هرمي و الكادميوم رباعي السطوح.
تم اجراء معالجة نظرية لهذه الليكندات المحضرة في الطور الغازي باستخدام برنامجي Hyper chem.8 and Gaussian program (GaussView Currently Available Versions (5.0.9) along with Gaussian 09 which is the latest in the Gaussian series of programs).
Abstract EN
A new mixed ligand complexes were prepared by reaction of quinoline-2-carboxylic acid (L1) and 4, 4 ⁄ dimethyl-2, 2 ⁄-bipyridyl (L2) with V (IV), Cr (III), Rh (III), Cd (II) and Pt (IV) ions.
These complexes were isolated and characterized by (FT-IR) and (UV-Vis) spectroscopy, elemental analysis, flame atomic absorption technique, thermogravimetric analysis, in addition to magnetic susceptibility and conductivity measurements.
Most complexes were mononuclear and with octahedral geometry, except Cd (II) with tetrahedral geometry, and V (IV) with square pyramidal geometry.
A theoretical treatment of the ligands and the prepared complexes in gas phase was done using two programs Hyperchem.8 and Gaussian program (GaussView Currently Available Versions (5.
0.
9) along with Gaussian 09 which is the latest in the Gaussian series of programs).
American Psychological Association (APA)
Ilyas, Mahasin Faysal Ahmad& Umran, Sahar Ismail. 2014. Mixed ligand complexes of quinoline-2-carboxylic acid and 4, 4 -dimethyl-2, 2 -bipyridyl with V (IV), Cr (III), Rh (III), Cd (II) and Pt (IV). Baghdad Science Journal،Vol. 11, no. 3, pp.1180-1191.
https://search.emarefa.net/detail/BIM-408763
Modern Language Association (MLA)
Ilyas, Mahasin Faysal Ahmad& Umran, Sahar Ismail. Mixed ligand complexes of quinoline-2-carboxylic acid and 4, 4 -dimethyl-2, 2 -bipyridyl with V (IV), Cr (III), Rh (III), Cd (II) and Pt (IV). Baghdad Science Journal Vol. 11, no. 3 (2014), pp.1180-1191.
https://search.emarefa.net/detail/BIM-408763
American Medical Association (AMA)
Ilyas, Mahasin Faysal Ahmad& Umran, Sahar Ismail. Mixed ligand complexes of quinoline-2-carboxylic acid and 4, 4 -dimethyl-2, 2 -bipyridyl with V (IV), Cr (III), Rh (III), Cd (II) and Pt (IV). Baghdad Science Journal. 2014. Vol. 11, no. 3, pp.1180-1191.
https://search.emarefa.net/detail/BIM-408763
Data Type
Journal Articles
Language
English
Notes
Text in English ; abstracts in English and Arabic.
Record ID
BIM-408763
