Synthesis and characterization of peroxo complexes of uranium (VI) with aroylhydrazone ligands
Joint Authors
Mahajan, Sandip
Singh, B.
Sheikh, H. N.
Kalsotra, B. L.
Source
Journal of Saudi Chemical Society
Issue
Vol. 18, Issue 5 (31 Dec. 2014), pp.494-501, 8 p.
Publisher
Publication Date
2014-12-31
Country of Publication
Saudi Arabia
No. of Pages
8
Main Subjects
Abstract EN
The uranium (VI) peroxo complexes containing aroylhydrazones ligands having composition [UO (O2) L-L (NO3) 2] ÆH2O (where L-L = Benzoic acid [1-(Furan-2-yl) methylene] hydrazide, Benzoic acid [ (thiophene-2-yl) methylene] hydrazide, Benzoic acid [1-(thiophene-2-yl) ethylidene] hydrazide, Benzoic acid (phenylmethylene) hydrazide, Benzoic acid [1-(anisol-3-yl) methylene] hydrazide and Benzoic acid [ (p-chlorobenzyl) methylene] hydrazide are reported.
The complexes were characterized by various physico-chemical techniques, viz.
elemental analysis, molar conductivity, magnetic susceptibility measurements, infra red, electronic, mass spectral and TGA / DTA studies.
These studies revealed that complexes are non-electrolytes and diamagnetic in nature.
The ligands are bound to metal in a bidentate mode.
Thermal analysis results provide conclusive evidence for the presence of water molecules in the complexes.
Mass spectra confirm the molecular mass of the complexes.
Antifungal activity of complexes revealed enhanced activity of complexes as compared to the corresponding ligands.
American Psychological Association (APA)
Singh, B.& Mahajan, Sandip& Sheikh, H. N.& Kalsotra, B. L.. 2014. Synthesis and characterization of peroxo complexes of uranium (VI) with aroylhydrazone ligands. Journal of Saudi Chemical Society،Vol. 18, no. 5, pp.494-501.
https://search.emarefa.net/detail/BIM-412784
Modern Language Association (MLA)
Mahajan, Sandip…[et al.]. Synthesis and characterization of peroxo complexes of uranium (VI) with aroylhydrazone ligands. Journal of Saudi Chemical Society Vol. 18, no. 5 (2014), pp.494-501.
https://search.emarefa.net/detail/BIM-412784
American Medical Association (AMA)
Singh, B.& Mahajan, Sandip& Sheikh, H. N.& Kalsotra, B. L.. Synthesis and characterization of peroxo complexes of uranium (VI) with aroylhydrazone ligands. Journal of Saudi Chemical Society. 2014. Vol. 18, no. 5, pp.494-501.
https://search.emarefa.net/detail/BIM-412784
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 500-501
Record ID
BIM-412784