Synthesis, Characterization, and Electrochemical Behaviour of Cobalt(II) and Nickel(II) Complexes with N2O2 Chelating Ligand 4,4′-(Biphenyl-4,4′-diyldinitrilo)dipentan-2-one
Joint Authors
Sibous, Lakhdar
Bentouhami, Embarek
Khan, Mustayeen Ahmad
Source
Journal of Inorganic Chemistry
Issue
Vol. 2013, Issue 2013 (31 Dec. 2013), pp.1-11, 11 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2013-09-03
Country of Publication
Egypt
No. of Pages
11
Main Subjects
Abstract EN
4,4′-Diaminobiphenyl reacts with 2,4-pentanedione in absolute ethanol in a molar ratio 1 : 2 to form mainly the product of [1 + 2] condensation, 4,4′-(biphenyl-4,4′-diyldinitrilo)dipentan-2-one (H2L).
The Schiff base was used as tetradentate chelating ligand to coordinate CoII and NiII chlorides leading to complexes where the ratio of metal ligand was found to be 2 : 1 or 2 : 2.
All the synthesized products were characterized by elemental analysis, infrared, electronic, and mass spectroscopy, 1H NMR, and DSC.
The electrochemical behaviour of the ligand and its complexes in DMF is also investigated.
American Psychological Association (APA)
Sibous, Lakhdar& Bentouhami, Embarek& Khan, Mustayeen Ahmad. 2013. Synthesis, Characterization, and Electrochemical Behaviour of Cobalt(II) and Nickel(II) Complexes with N2O2 Chelating Ligand 4,4′-(Biphenyl-4,4′-diyldinitrilo)dipentan-2-one. Journal of Inorganic Chemistry،Vol. 2013, no. 2013, pp.1-11.
https://search.emarefa.net/detail/BIM-446732
Modern Language Association (MLA)
Sibous, Lakhdar…[et al.]. Synthesis, Characterization, and Electrochemical Behaviour of Cobalt(II) and Nickel(II) Complexes with N2O2 Chelating Ligand 4,4′-(Biphenyl-4,4′-diyldinitrilo)dipentan-2-one. Journal of Inorganic Chemistry No. 2013 (2013), pp.1-11.
https://search.emarefa.net/detail/BIM-446732
American Medical Association (AMA)
Sibous, Lakhdar& Bentouhami, Embarek& Khan, Mustayeen Ahmad. Synthesis, Characterization, and Electrochemical Behaviour of Cobalt(II) and Nickel(II) Complexes with N2O2 Chelating Ligand 4,4′-(Biphenyl-4,4′-diyldinitrilo)dipentan-2-one. Journal of Inorganic Chemistry. 2013. Vol. 2013, no. 2013, pp.1-11.
https://search.emarefa.net/detail/BIM-446732
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-446732