Selective Hydrogenation of p-Chloronitrobenzene on Nanosized PdNiB Catalysts
Joint Authors
Source
Issue
Vol. 2013, Issue 2013 (31 Dec. 2013), pp.1-10, 10 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2013-03-18
Country of Publication
Egypt
No. of Pages
10
Main Subjects
Engineering Sciences and Information Technology
Chemistry
Abstract EN
A series of PdNiB bimetallic nanoalloy catalysts with various Pd contents was prepared.
Pd was well dispersed in NiB.
Even adding a small amount of Pd in NiB had a significant effect on activity and selectivity in hydrogenation of p-chloronitrobenzene (p-CNB) to p-chloroaniline (p-CAN).
High activity and selectivity on PdNiB could be attributed to both ensemble effect and electronic effect.
The particle size in PdNiB decreased with an increase in Pd content.
Electron-enriched Ni could activate the polar-NO2 groups of p-CNB and depress the dehalogenation of p-CAN.
American Psychological Association (APA)
Chen, Yu-Wen& Lee, Der-Shing. 2013. Selective Hydrogenation of p-Chloronitrobenzene on Nanosized PdNiB Catalysts. Journal of Nanoparticles،Vol. 2013, no. 2013, pp.1-10.
https://search.emarefa.net/detail/BIM-448238
Modern Language Association (MLA)
Chen, Yu-Wen& Lee, Der-Shing. Selective Hydrogenation of p-Chloronitrobenzene on Nanosized PdNiB Catalysts. Journal of Nanoparticles No. 2013 (2013), pp.1-10.
https://search.emarefa.net/detail/BIM-448238
American Medical Association (AMA)
Chen, Yu-Wen& Lee, Der-Shing. Selective Hydrogenation of p-Chloronitrobenzene on Nanosized PdNiB Catalysts. Journal of Nanoparticles. 2013. Vol. 2013, no. 2013, pp.1-10.
https://search.emarefa.net/detail/BIM-448238
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-448238