Synthesis, Spectral, Thermal, Electrochemical, and Biocidal Activity of TolylBenzyl Dithiocarbonates of Zinc(II)
Joint Authors
Andotra, Savit
Kalgotra, Nidhi
Kumar, Sandeep
Gupta, Bhawana
Pandey, Sushil Kumar
Source
International Journal of Inorganic Chemistry
Issue
Vol. 2013, Issue 2013 (31 Dec. 2013), pp.1-12, 12 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2013-12-24
Country of Publication
Egypt
No. of Pages
12
Main Subjects
Abstract EN
Tolyl/benzyl dithiocarbonates of zinc(II) [(o-,m-,p-CH3C6H4 and C6H5CH2OCS2)2Zn] have been synthesized in 1 : 2 molar ratio by the reaction of zinc chloride, ZnCl2, with sodium salts of tolyl/benzyl dithiocarbonates (o-,m-,p-CH3C6H4O/C6H5CH2O)CS2Na, in aqueous medium.
These complexes were further reacted with nitrogen and phosphorous donor ligands to obtain donor stabilized complex of the type [[(o-,m-,p-CH3C6H4 and C6H5CH2)OCS2]2Zn.nL], (L = Bipy, Phen for n=1 and PPh3, Py for n=2).
These complexes were characterised by elemental analysis, mass, IR, and NMR (1H, 13C, and 31P) spectroscopies.
The thermal analysis (TGA/DTA), cyclic voltammetry, and SEM have also been done.
Distorted tetrahedral and octahedral geometries around the Zn(II) metal are proposed.
These complexes have depicted potential antibacterial and antifungal activity.
American Psychological Association (APA)
Kalgotra, Nidhi& Gupta, Bhawana& Andotra, Savit& Kumar, Sandeep& Pandey, Sushil Kumar. 2013. Synthesis, Spectral, Thermal, Electrochemical, and Biocidal Activity of TolylBenzyl Dithiocarbonates of Zinc(II). International Journal of Inorganic Chemistry،Vol. 2013, no. 2013, pp.1-12.
https://search.emarefa.net/detail/BIM-448487
Modern Language Association (MLA)
Kalgotra, Nidhi…[et al.]. Synthesis, Spectral, Thermal, Electrochemical, and Biocidal Activity of TolylBenzyl Dithiocarbonates of Zinc(II). International Journal of Inorganic Chemistry No. 2013 (2013), pp.1-12.
https://search.emarefa.net/detail/BIM-448487
American Medical Association (AMA)
Kalgotra, Nidhi& Gupta, Bhawana& Andotra, Savit& Kumar, Sandeep& Pandey, Sushil Kumar. Synthesis, Spectral, Thermal, Electrochemical, and Biocidal Activity of TolylBenzyl Dithiocarbonates of Zinc(II). International Journal of Inorganic Chemistry. 2013. Vol. 2013, no. 2013, pp.1-12.
https://search.emarefa.net/detail/BIM-448487
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-448487
