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The Effect of Stereochemistry on Sodium Ion Complexation in Nucleoside-Metallacarborane Conjugates
Joint Authors
Olejniczak, Agnieszka B.
Milecki, Jan
Schroeder, Grzegorz
Source
Bioinorganic Chemistry and Applications
Issue
Vol. 2010, Issue 2010 (31 Dec. 2010), pp.1-9, 9 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2010-07-01
Country of Publication
Egypt
No. of Pages
9
Main Subjects
Abstract EN
Conjugates of purine and pyrimidine nucleosides: thymidine and 2′-deoxyguanosine with cobalt-metallacarborane were studied for their sodium ion complexing properties.
Formation of stable complexes of 1 : 1 stoichiometry was proved by ESI MS spectroscopy and 23Na NMR.
Equilibrium constants and energies of complex formation were calculated.
Complexation of alkali-metals by nucleoside-metallacarborane conjugates may affect the physicochemical and biological properties of the conjugates and should be taken into consideration during biological evaluation of these types of modifications.
American Psychological Association (APA)
Olejniczak, Agnieszka B.& Milecki, Jan& Schroeder, Grzegorz. 2010. The Effect of Stereochemistry on Sodium Ion Complexation in Nucleoside-Metallacarborane Conjugates. Bioinorganic Chemistry and Applications،Vol. 2010, no. 2010, pp.1-9.
https://search.emarefa.net/detail/BIM-453656
Modern Language Association (MLA)
Olejniczak, Agnieszka B.…[et al.]. The Effect of Stereochemistry on Sodium Ion Complexation in Nucleoside-Metallacarborane Conjugates. Bioinorganic Chemistry and Applications No. 2010 (2010), pp.1-9.
https://search.emarefa.net/detail/BIM-453656
American Medical Association (AMA)
Olejniczak, Agnieszka B.& Milecki, Jan& Schroeder, Grzegorz. The Effect of Stereochemistry on Sodium Ion Complexation in Nucleoside-Metallacarborane Conjugates. Bioinorganic Chemistry and Applications. 2010. Vol. 2010, no. 2010, pp.1-9.
https://search.emarefa.net/detail/BIM-453656
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-453656