The Effect of Stereochemistry on Sodium Ion Complexation in Nucleoside-Metallacarborane Conjugates

Joint Authors

Olejniczak, Agnieszka B.
Milecki, Jan
Schroeder, Grzegorz

Source

Bioinorganic Chemistry and Applications

Issue

Vol. 2010, Issue 2010 (31 Dec. 2010), pp.1-9, 9 p.

Publisher

Hindawi Publishing Corporation

Publication Date

2010-07-01

Country of Publication

Egypt

No. of Pages

9

Main Subjects

Biology

Abstract EN

Conjugates of purine and pyrimidine nucleosides: thymidine and 2′-deoxyguanosine with cobalt-metallacarborane were studied for their sodium ion complexing properties.

Formation of stable complexes of 1 : 1 stoichiometry was proved by ESI MS spectroscopy and 23Na NMR.

Equilibrium constants and energies of complex formation were calculated.

Complexation of alkali-metals by nucleoside-metallacarborane conjugates may affect the physicochemical and biological properties of the conjugates and should be taken into consideration during biological evaluation of these types of modifications.

American Psychological Association (APA)

Olejniczak, Agnieszka B.& Milecki, Jan& Schroeder, Grzegorz. 2010. The Effect of Stereochemistry on Sodium Ion Complexation in Nucleoside-Metallacarborane Conjugates. Bioinorganic Chemistry and Applications،Vol. 2010, no. 2010, pp.1-9.
https://search.emarefa.net/detail/BIM-453656

Modern Language Association (MLA)

Olejniczak, Agnieszka B.…[et al.]. The Effect of Stereochemistry on Sodium Ion Complexation in Nucleoside-Metallacarborane Conjugates. Bioinorganic Chemistry and Applications No. 2010 (2010), pp.1-9.
https://search.emarefa.net/detail/BIM-453656

American Medical Association (AMA)

Olejniczak, Agnieszka B.& Milecki, Jan& Schroeder, Grzegorz. The Effect of Stereochemistry on Sodium Ion Complexation in Nucleoside-Metallacarborane Conjugates. Bioinorganic Chemistry and Applications. 2010. Vol. 2010, no. 2010, pp.1-9.
https://search.emarefa.net/detail/BIM-453656

Data Type

Journal Articles

Language

English

Notes

Includes bibliographical references

Record ID

BIM-453656