Proton Transfer Equilibria and Critical Behavior of H-Bonding
Joint Authors
Sobczyk, L.
Rospenk, M.
Obrzud, M.
Czarnik-Matusewicz, B.
Source
Journal of Atomic, Molecular, and Optical Physics
Issue
Vol. 2012, Issue 2012 (31 Dec. 2012), pp.1-10, 10 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2012-06-21
Country of Publication
Egypt
No. of Pages
10
Main Subjects
Abstract EN
The aim of the present paper is an analysis of the hydrogen bond properties for the acid-base systems depending on the ability to the proton transfer in the formulation of the Brönsted approach.
After definition of the proton transfer equilibrium expressed by using the equation log KPT=ξΔpKN, various examples of different physical properties, such as dipole moments, IR spectra, and nuclear magnetic resonances, are presented which correlate with the ΔpKN value.
In such a way, a critical state of hydrogen bonding can be defined that corresponds to the potential of the proton motion for either single minimum or double minimum with low barrier.
A particular attention in this paper found electronic spectra which have not been analysed so far and the quantitative analysis of the vibrational polarizability which can reach very high values of the order of electronic polarizability.
American Psychological Association (APA)
Sobczyk, L.& Czarnik-Matusewicz, B.& Rospenk, M.& Obrzud, M.. 2012. Proton Transfer Equilibria and Critical Behavior of H-Bonding. Journal of Atomic, Molecular, and Optical Physics،Vol. 2012, no. 2012, pp.1-10.
https://search.emarefa.net/detail/BIM-455448
Modern Language Association (MLA)
Sobczyk, L.…[et al.]. Proton Transfer Equilibria and Critical Behavior of H-Bonding. Journal of Atomic, Molecular, and Optical Physics No. 2012 (2012), pp.1-10.
https://search.emarefa.net/detail/BIM-455448
American Medical Association (AMA)
Sobczyk, L.& Czarnik-Matusewicz, B.& Rospenk, M.& Obrzud, M.. Proton Transfer Equilibria and Critical Behavior of H-Bonding. Journal of Atomic, Molecular, and Optical Physics. 2012. Vol. 2012, no. 2012, pp.1-10.
https://search.emarefa.net/detail/BIM-455448
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-455448