Accelerations in the Lactonization of Trimethyl Lock Systems Are due to Proximity Orientation and not to Strain Effects

Author

Karaman, Rafik

Source

Research Letters in Organic Chemistry

Issue

Vol. 2009, Issue 2009 (31 Dec. 2009), pp.1-5, 5 p.

Publisher

Hindawi Publishing Corporation

Publication Date

2009-03-26

Country of Publication

Egypt

No. of Pages

5

Main Subjects

Chemistry

Abstract EN

DFT at B3LYP/6-31G(d,p) and HF at 6-31G and AM1 semiempirical calculations of thermodynamc and kinetic parameters for the trimethyl lock system (an important enzyme model) indicate that the remarkable enhancement in the lactonizations is largely the result of a proximity orientation as opposed to the currently advanced strain effect.

American Psychological Association (APA)

Karaman, Rafik. 2009. Accelerations in the Lactonization of Trimethyl Lock Systems Are due to Proximity Orientation and not to Strain Effects. Research Letters in Organic Chemistry،Vol. 2009, no. 2009, pp.1-5.
https://search.emarefa.net/detail/BIM-456522

Modern Language Association (MLA)

Karaman, Rafik. Accelerations in the Lactonization of Trimethyl Lock Systems Are due to Proximity Orientation and not to Strain Effects. Research Letters in Organic Chemistry No. 2009 (2009), pp.1-5.
https://search.emarefa.net/detail/BIM-456522

American Medical Association (AMA)

Karaman, Rafik. Accelerations in the Lactonization of Trimethyl Lock Systems Are due to Proximity Orientation and not to Strain Effects. Research Letters in Organic Chemistry. 2009. Vol. 2009, no. 2009, pp.1-5.
https://search.emarefa.net/detail/BIM-456522

Data Type

Journal Articles

Language

English

Notes

Includes bibliographical references

Record ID

BIM-456522