Exchange Interaction in Complex Bis[(1,3-Dithiole-2-Thione-4,5-Dithiolato)-di-(Carbonyl)-Cyclopentadienyl Iron(II)]
Joint Authors
Feher, A.
Presniakov, I. A.
Radvákova, A.
Starodub, V. A.
Kajňaková, M.
Vitushkina, S. V.
Sobolev, A. V.
Ziolkovskiy, D. V.
Source
Research Letters in Inorganic Chemistry
Issue
Vol. 2009, Issue 2009 (31 Dec. 2009), pp.1-4, 4 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2009-09-24
Country of Publication
Egypt
No. of Pages
4
Main Subjects
Abstract EN
The splitting of the quasidegenerate electronic states in dinuclear bis[(1,3-dithiole-2-thione-4,5-dithiolato)-di-(carbonyl)-cyclopentadienyliron (II)] complex with the bridging, S–S coupled, dimerized sulfur-rich dithiolate ligands, [Fe(C5H5)(CO)2(C3S5-C3S5)Fe(C5H5)(CO)2] (I) was found by the means of Mössbauer spectroscopy and by the measurement of the temperature dependence of magnetic susceptibility in a wide temperature range from 2 K to 300 K.
The experimental results were confirmed by the calculations of the singlet and triplet states of the complex, as well as of the distribution of spin density within the bounds of the DFT method in the B3LYP/6-31(dp)G basis.
In the more stable triplet state, the spin density is significantly delocalized, which is a characteristic of olefindithiolate complexes.
American Psychological Association (APA)
Vitushkina, S. V.& Ziolkovskiy, D. V.& Starodub, V. A.& Presniakov, I. A.& Sobolev, A. V.& Kajňaková, M.…[et al.]. 2009. Exchange Interaction in Complex Bis[(1,3-Dithiole-2-Thione-4,5-Dithiolato)-di-(Carbonyl)-Cyclopentadienyl Iron(II)]. Research Letters in Inorganic Chemistry،Vol. 2009, no. 2009, pp.1-4.
https://search.emarefa.net/detail/BIM-456790
Modern Language Association (MLA)
Vitushkina, S. V.…[et al.]. Exchange Interaction in Complex Bis[(1,3-Dithiole-2-Thione-4,5-Dithiolato)-di-(Carbonyl)-Cyclopentadienyl Iron(II)]. Research Letters in Inorganic Chemistry No. 2009 (2009), pp.1-4.
https://search.emarefa.net/detail/BIM-456790
American Medical Association (AMA)
Vitushkina, S. V.& Ziolkovskiy, D. V.& Starodub, V. A.& Presniakov, I. A.& Sobolev, A. V.& Kajňaková, M.…[et al.]. Exchange Interaction in Complex Bis[(1,3-Dithiole-2-Thione-4,5-Dithiolato)-di-(Carbonyl)-Cyclopentadienyl Iron(II)]. Research Letters in Inorganic Chemistry. 2009. Vol. 2009, no. 2009, pp.1-4.
https://search.emarefa.net/detail/BIM-456790
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-456790
