Regional-Scale Ozone Deposition to North-East Atlantic Waters

Abstract EN

A regional climate model is used to evaluate dry deposition of ozone over the North East Atlantic.

Results are presented for a deposition scheme accounting for turbulent and chemical enhancement of oceanic ozone deposition and a second non-chemical, parameterised gaseous dry deposition scheme.

The first deposition scheme was constrained to account for sea-surface ozone-iodide reactions and the sensitivity of modelled ozone concentrations to oceanic iodide concentration was investigated.

Simulations were also performed using nominal reaction rate derived from in-situ ozone deposition measurements and using a preliminary representation of organic chemistry.

Results show insensitivity of ambient ozone concentrations modelled by the chemical-enhanced scheme to oceanic iodide concentrations, and iodide reactions alone cannot account for observed deposition velocities.

Consequently, we suggest a missing chemical sink due to reactions of ozone with organic matter at the air-sea interface.

Ozone loss rates are estimated to be in the range of 0.5–6 ppb per day.

A potentially significant ozone-driven flux of iodine to the atmosphere is estimated to be in the range of 2.5–500 M molec cm−2 s−1, leading to a mixing-layer enhancement of organo-iodine concentrations of 0.1–22.0 ppt, with an average increase in the N.E.

Atlantic of around 4 ppt per day.