Evaluation of Electronic Effects in the Solvolyses of p-Methylphenyl and p-Chlorophenyl Chlorothionoformate Esters
Joint Authors
Sansbury, Brett M.
D'Souza, Malcolm J.
Kevill, Dennis N.
Hampton, Olivia N.
Source
Issue
Vol. 2013, Issue 2013 (31 Dec. 2013), pp.1-9, 9 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2012-07-19
Country of Publication
Egypt
No. of Pages
9
Main Subjects
Abstract EN
The solvolyses of p-tolyl chlorothionoformate and p-chlorophenyl chlorothionoformate are studied in a variety of organic mixtures of widely varying nucleophilicity and ionizing power values.
This solvolytic data is accumulated at 25.0°C using the titration method.
An analysis of the rate data using the extended (two-term) Grunwald-Winstein equation and the concept of similarity of substrates based on their l/m ratios shows the occurrence of simultaneous side-by-side addition-elimination and unimolecular SN1 mechanisms.
American Psychological Association (APA)
D'Souza, Malcolm J.& Hampton, Olivia N.& Sansbury, Brett M.& Kevill, Dennis N.. 2012. Evaluation of Electronic Effects in the Solvolyses of p-Methylphenyl and p-Chlorophenyl Chlorothionoformate Esters. Journal of Chemistry،Vol. 2013, no. 2013, pp.1-9.
https://search.emarefa.net/detail/BIM-457208
Modern Language Association (MLA)
D'Souza, Malcolm J.…[et al.]. Evaluation of Electronic Effects in the Solvolyses of p-Methylphenyl and p-Chlorophenyl Chlorothionoformate Esters. Journal of Chemistry No. 2013 (2013), pp.1-9.
https://search.emarefa.net/detail/BIM-457208
American Medical Association (AMA)
D'Souza, Malcolm J.& Hampton, Olivia N.& Sansbury, Brett M.& Kevill, Dennis N.. Evaluation of Electronic Effects in the Solvolyses of p-Methylphenyl and p-Chlorophenyl Chlorothionoformate Esters. Journal of Chemistry. 2012. Vol. 2013, no. 2013, pp.1-9.
https://search.emarefa.net/detail/BIM-457208
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-457208
