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Synthesis and Characterization of Bis(4-methylbenzylammonium) Tetrachloridocadmate(II)
Joint Authors
Ben Nasr, C.
Kefi, R.
Lefebvre, F.
Zeller, M.
Source
International Journal of Inorganic Chemistry
Issue
Vol. 2011, Issue 2011 (31 Dec. 2011), pp.1-7, 7 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2012-01-31
Country of Publication
Egypt
No. of Pages
7
Main Subjects
Abstract EN
The crystal structure of the new inorganic-organic hybrid compound [4-CH3C6H4CH2NH3]2[CdCl4] has been determined by single crystal X-ray diffraction.
The compound crystallizes in the orthorhombic space group Pnma with lattice parameters a=10.721(2), b=33.986(6), c=5.326(1) Å, β=97.222(1)°, V=1940.8(7) Å3, and Z=4.
The framework of the title compound is built upon layers parallel to (010) made up from corner-sharing CdCl6 octahedra.
4-Methylbenzylammonium cations are situated between the layers and connect them via an N–H⋯Cl hydrogen bonding network.
The Cd atom is located on an inversion centre, and the coordination environment is described as distorted octahedral.
Solid state 13C CP-MAS NMR spectroscopy is in agreement with the X-ray structure.
DFT calculations allow the attribution of the carbon peaks to the independent crystallographic sites.
Thermal analysis and infrared spectroscopy were also used to characterize the complex.
American Psychological Association (APA)
Kefi, R.& Zeller, M.& Lefebvre, F.& Ben Nasr, C.. 2012. Synthesis and Characterization of Bis(4-methylbenzylammonium) Tetrachloridocadmate(II). International Journal of Inorganic Chemistry،Vol. 2011, no. 2011, pp.1-7.
https://search.emarefa.net/detail/BIM-459432
Modern Language Association (MLA)
Kefi, R.…[et al.]. Synthesis and Characterization of Bis(4-methylbenzylammonium) Tetrachloridocadmate(II). International Journal of Inorganic Chemistry No. 2011 (2011), pp.1-7.
https://search.emarefa.net/detail/BIM-459432
American Medical Association (AMA)
Kefi, R.& Zeller, M.& Lefebvre, F.& Ben Nasr, C.. Synthesis and Characterization of Bis(4-methylbenzylammonium) Tetrachloridocadmate(II). International Journal of Inorganic Chemistry. 2012. Vol. 2011, no. 2011, pp.1-7.
https://search.emarefa.net/detail/BIM-459432
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-459432