Synthesis, Structure, and Thermal Stability of Supramolecular Polymers with 1D Chain : [M(BPP)2(TBTA)(H2O)2]n[M=Mn(1),Co(2)]
Joint Authors
Gao, Ling-Ling
Liu, Yan
Lv, Xu-Yan
Hu, Tuo-Ping
Liu, Jian-Feng
Source
International Journal of Inorganic Chemistry
Issue
Vol. 2012, Issue 2012 (31 Dec. 2012), pp.1-6, 6 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2012-04-17
Country of Publication
Egypt
No. of Pages
6
Main Subjects
Abstract EN
Two supramolecular polymers [M(BPP)2(TBTA)(H2O)2]n[M=Mn(1),Co(2)] have been constructed from 2,3,5,6-tetrabromoterephthalic acid (H2TBTA) and 1,3-bis(4-pyridyl)propane (BPP) ligands in water-methanol dissolvant.
Single-crystal X-ray and powder diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis were employed to characterize all samples.
Both of the complex compounds 1 and 2 belong to triclinic crystal system with P-1 space group.
The crystal structures analysis indicates that the metal atom coordinated by two carboxylate groups from different TBTA ligands, two BPP, molecules and two H2O molecules formed a slightly distorted octahedral configuration.
The compounds of 1 and 2 are 1D chains made with TBTA spacers, BPP molecules, and H2O molecules.
American Psychological Association (APA)
Liu, Yan& Gao, Ling-Ling& Lv, Xu-Yan& Liu, Jian-Feng& Hu, Tuo-Ping. 2012. Synthesis, Structure, and Thermal Stability of Supramolecular Polymers with 1D Chain : [M(BPP)2(TBTA)(H2O)2]n[M=Mn(1),Co(2)]. International Journal of Inorganic Chemistry،Vol. 2012, no. 2012, pp.1-6.
https://search.emarefa.net/detail/BIM-459463
Modern Language Association (MLA)
Liu, Yan…[et al.]. Synthesis, Structure, and Thermal Stability of Supramolecular Polymers with 1D Chain : [M(BPP)2(TBTA)(H2O)2]n[M=Mn(1),Co(2)]. International Journal of Inorganic Chemistry No. 2012 (2012), pp.1-6.
https://search.emarefa.net/detail/BIM-459463
American Medical Association (AMA)
Liu, Yan& Gao, Ling-Ling& Lv, Xu-Yan& Liu, Jian-Feng& Hu, Tuo-Ping. Synthesis, Structure, and Thermal Stability of Supramolecular Polymers with 1D Chain : [M(BPP)2(TBTA)(H2O)2]n[M=Mn(1),Co(2)]. International Journal of Inorganic Chemistry. 2012. Vol. 2012, no. 2012, pp.1-6.
https://search.emarefa.net/detail/BIM-459463
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-459463