Hybrid Polymer-Immobilized Nanosized Pd Catalysts for Hydrogenation Reaction Obtained via Frontal Polymerization
Joint Authors
Pomogailo, Anatolii D.
Dzhardimalieva, Gulzhian I.
Source
Issue
Vol. 2013, Issue 2013 (31 Dec. 2013), pp.1-12, 12 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2012-12-13
Country of Publication
Egypt
No. of Pages
12
Main Subjects
Engineering Sciences and Information Technology
Chemistry
Abstract EN
A new approach to the synthesis of mixed-type immobilized catalysts by frontal polymerization of metal-containing monomer in the presence of highly dispersed mineral support has been developed.
Synthesis of the acrylamide Pd(II) nitrate complex, Pd(CH2=CHCONH2)2 (NO3)2 (PdAAm), on the SiO2 (Al2O3, C) surface and its consequent frontal polymerization and reduction lead to the formation of organic-inorganic composites with polymer-stabilized Pd nanoparticles.
The immobilized metal complexes and palladium nanoparticles were characterized by various physical and chemical methods.
The synthesized hybrid nanocomposites are efficient and selective catalysts for hydrogenation of cyclohexene, alkene, and acetylene alcohols, as well as di- and trinitrotoluene.
Catalyst intermediates separated by nondestructive testing method have been described and changing in the palladium charge during the catalytic process has been identified.
American Psychological Association (APA)
Pomogailo, Anatolii D.& Dzhardimalieva, Gulzhian I.. 2012. Hybrid Polymer-Immobilized Nanosized Pd Catalysts for Hydrogenation Reaction Obtained via Frontal Polymerization. Journal of Catalysts،Vol. 2013, no. 2013, pp.1-12.
https://search.emarefa.net/detail/BIM-459625
Modern Language Association (MLA)
Pomogailo, Anatolii D.& Dzhardimalieva, Gulzhian I.. Hybrid Polymer-Immobilized Nanosized Pd Catalysts for Hydrogenation Reaction Obtained via Frontal Polymerization. Journal of Catalysts No. 2013 (2013), pp.1-12.
https://search.emarefa.net/detail/BIM-459625
American Medical Association (AMA)
Pomogailo, Anatolii D.& Dzhardimalieva, Gulzhian I.. Hybrid Polymer-Immobilized Nanosized Pd Catalysts for Hydrogenation Reaction Obtained via Frontal Polymerization. Journal of Catalysts. 2012. Vol. 2013, no. 2013, pp.1-12.
https://search.emarefa.net/detail/BIM-459625
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-459625