Crystal Structure and Thermal Behavior of Two New Supramolecular Complexes Templated with 1,2,4,5-Benzenetetracarboxylic Acid
Joint Authors
Gao, Ling-Ling
Liu, Yan
Lv, Xu-Yan
Hu, Tuo-Ping
Liu, Jian-Feng
Source
International Journal of Inorganic Chemistry
Issue
Vol. 2012, Issue 2012 (31 Dec. 2012), pp.1-6, 6 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2012-05-21
Country of Publication
Egypt
No. of Pages
6
Main Subjects
Abstract EN
Templated coordination polymers [Ni(H2O)4(bipy)](BTA)0.5·H2O (1) and [Co(H2O)4(bipy)](BTA)0.5·H2O (2) (bipy = 4,4′-Bipyridine, H4BTA = 1,2,4,5-Benzenetetracarboxylic Acid) were synthesized and characterized by single-crystal X-ray diffraction, powder diffraction, elemental analysis, IR, and thermogravimetric analysis.
Both of complexes 1 and 2 are monoclinic crystal system, C2/c space group, and isostructural.
The unit of the structure, the metal ion is coordinated by four water molecules and two bipy molecules, is a slightly distorted octahedral configuration, and the carboxyl group from BTA4- ion doesn't coordinate with the metal ion, the H-bonding interactions further connect the mononuclear molecules to generate a 3D supramolecular complex.
American Psychological Association (APA)
Gao, Ling-Ling& Liu, Yan& Lv, Xu-Yan& Liu, Jian-Feng& Hu, Tuo-Ping. 2012. Crystal Structure and Thermal Behavior of Two New Supramolecular Complexes Templated with 1,2,4,5-Benzenetetracarboxylic Acid. International Journal of Inorganic Chemistry،Vol. 2012, no. 2012, pp.1-6.
https://search.emarefa.net/detail/BIM-460895
Modern Language Association (MLA)
Gao, Ling-Ling…[et al.]. Crystal Structure and Thermal Behavior of Two New Supramolecular Complexes Templated with 1,2,4,5-Benzenetetracarboxylic Acid. International Journal of Inorganic Chemistry No. 2012 (2012), pp.1-6.
https://search.emarefa.net/detail/BIM-460895
American Medical Association (AMA)
Gao, Ling-Ling& Liu, Yan& Lv, Xu-Yan& Liu, Jian-Feng& Hu, Tuo-Ping. Crystal Structure and Thermal Behavior of Two New Supramolecular Complexes Templated with 1,2,4,5-Benzenetetracarboxylic Acid. International Journal of Inorganic Chemistry. 2012. Vol. 2012, no. 2012, pp.1-6.
https://search.emarefa.net/detail/BIM-460895
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-460895