Synthesis and Studies on S-Triazine-Based Ligand and Its Metal Complexes
Joint Authors
Sheela, C. D.
Tharmaraj, P.
Anitha, C.
Shanmugakala, R.
Source
International Journal of Inorganic Chemistry
Issue
Vol. 2012, Issue 2012 (31 Dec. 2012), pp.1-7, 7 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2012-12-17
Country of Publication
Egypt
No. of Pages
7
Main Subjects
Abstract EN
Tridentate chelate complexes of ML type (where M = Cu(II), Ni(II), and Co(II)) have been synthesized from triazine-based ligand 4,6-bis(5-mercapto-1,3,4-thiadiazol-amine)2-phenylamino-1,3,5-triazine (BMTDT).
Microanalytical data, magnetic susceptibility measurements, IR, 1H NMR, UV-vis, mass, and EPR spectral techniques were used to characterise the structure of chelates.
The electronic absorption spectra and magnetic susceptibility measurements suggest that metal complexes show square pyramidal geometry.
The electrochemical behavior of copper(II) complex is studied by cyclic voltammetry.
All synthesized compounds may serve as potential photoactive materials as indicated from their characteristic fluorescence properties.
The second harmonic generation efficiency (SHG) of the ligand and metal complexes has been found to be higher than that of urea and KDP.
The antimicrobial activity of the ligand and metal(II) complexes against the species Shigella, Chromobacterium, Staphylococcus aureus, Candida albicans, and Aspergillus niger has been carried out and compared with the standard one.
American Psychological Association (APA)
Shanmugakala, R.& Tharmaraj, P.& Sheela, C. D.& Anitha, C.. 2012. Synthesis and Studies on S-Triazine-Based Ligand and Its Metal Complexes. International Journal of Inorganic Chemistry،Vol. 2012, no. 2012, pp.1-7.
https://search.emarefa.net/detail/BIM-461572
Modern Language Association (MLA)
Shanmugakala, R.…[et al.]. Synthesis and Studies on S-Triazine-Based Ligand and Its Metal Complexes. International Journal of Inorganic Chemistry No. 2012 (2012), pp.1-7.
https://search.emarefa.net/detail/BIM-461572
American Medical Association (AMA)
Shanmugakala, R.& Tharmaraj, P.& Sheela, C. D.& Anitha, C.. Synthesis and Studies on S-Triazine-Based Ligand and Its Metal Complexes. International Journal of Inorganic Chemistry. 2012. Vol. 2012, no. 2012, pp.1-7.
https://search.emarefa.net/detail/BIM-461572
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-461572