High Tap Density Spherical Li[Ni0.5Mn0.3Co0.2]O2 Cathode Material Synthesized via Continuous Hydroxide Coprecipitation Method for Advanced Lithium-Ion Batteries

Abstract EN

Spherical [Ni0.5Mn0.3Co0.2](OH)2 precursor with narrow size distribution and high tap density has been successfully synthesized by a continuous hydroxide coprecipitation, and Li[Ni0.5Mn0.3Co0.2]O2 is then prepared by mixing the precursor with 6% excess Li2CO3 followed by calcinations.

The tap density of the obtained Li[Ni0.5Mn0.3Co0.2]O2 powder is as high as 2.61 g cm−3.

The powders are characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM), particle size distribution (PSD), and charge/discharge cycling.

The XRD studies show that the prepared Li[Ni0.5Mn0.3Co0.2]O2 has a well-ordered layered structure without any impurity phases.

Good packing properties of spherical secondary particles (about 12 μm) consisted of a large number of tiny-thin plate-shape primary particles (less than 1 μm), which can be identified from the SEM observations.

In the voltage range of 3.0–4.3 V and 2.5–4.6 V, Li[Ni0.5Mn0.3Co0.2]O2 delivers the initial discharge capacity of approximately 175 and 214 mAh g−1 at a current density of 32 mA g−1, and the capacity retention after 50 cycles reaches 98.8% and 90.2%, respectively.

Besides, it displays good high-temperature characteristics and excellent rate capability.