Analysis of Bio-Obtainable Endocrine Disrupting Metals in River Water and Sediment, Sewage InfluentEffluent, Sludge, Leachate, and Concentrated Leachate, in the Irish Midlands Shannon Catchment

Joint Authors

Roche, James J.
Fogarty, Andrew M.
Reid, Antoinette M.
Brougham, Concepta A.

Source

International Journal of Analytical Chemistry

Issue

Vol. 2009, Issue 2009 (31 Dec. 2009), pp.1-12, 12 p.

Publisher

Hindawi Publishing Corporation

Publication Date

2010-02-03

Country of Publication

Egypt

No. of Pages

12

Main Subjects

Chemistry
Science

Abstract EN

The application of an acid digestion and subsequent solid-phase extraction (SPE) procedure were implemented as preliminary treatments prior to quantifying the levels of potentially endocrine disrupting metals (EDMs) in a variety of solid and liquid matrices.

These included (solid) river sediment, leachate sediment and sewage sludge and also (liquid) river water, landfill leachate, concentrated leachate, sewage influent, and sewage effluent, sampled in the Irish Midlands.

The total concentrations of cobalt (Co), cadmium (Cd), copper (Cu), chromium (Cr), nickel (Ni), lead (Pb), zinc (Zn), and manganese (Mn), after extraction and preconcentration, were determined by atomic absorption spectroscopy (AAS).

Mercury (Hg) in sediment and sludge was determined using cold-vapour atomic fluorescence spectroscopy (AFS).

For sewage sludge maximum values (mg/kgdw) of 4700 Ni, 1642 Mn, 100.0 Cd, 3400 Zn, 36.70 Co, 750.0 Pb, 485.8 Cr, and 1003 Cu were determined whilst in leachate sediment, maximum values (mg/kgdw) of 32.10 Ni, 815.0 Mn, 32.78 Cd, 230.3 Zn, 26.73 Co, 3525 Pb, 124.9 Cr, and 50.13 Cu were found.

Over several months, the data showed elevated levels in sewage influents, effluents, and sludges compared to a battery of adjacent river water samples and corresponding sediments.

There was a definite trend for target values for sediments to be exceeded, while intervention values were only exceeded for cadmium.

Overall the pattern in terms of concentration was sewage > leachate > river matrices.

A nonparametric assessment of the effect of sewage treatment method on median metal levels in sludge revealed statistically significant differences at the 95% level of confidence for Co, Cr, and Hg and at the 90% level of confidence for Cd.

American Psychological Association (APA)

Reid, Antoinette M.& Brougham, Concepta A.& Fogarty, Andrew M.& Roche, James J.. 2010. Analysis of Bio-Obtainable Endocrine Disrupting Metals in River Water and Sediment, Sewage InfluentEffluent, Sludge, Leachate, and Concentrated Leachate, in the Irish Midlands Shannon Catchment. International Journal of Analytical Chemistry،Vol. 2009, no. 2009, pp.1-12.
https://search.emarefa.net/detail/BIM-463650

Modern Language Association (MLA)

Reid, Antoinette M.…[et al.]. Analysis of Bio-Obtainable Endocrine Disrupting Metals in River Water and Sediment, Sewage InfluentEffluent, Sludge, Leachate, and Concentrated Leachate, in the Irish Midlands Shannon Catchment. International Journal of Analytical Chemistry No. 2009 (2009), pp.1-12.
https://search.emarefa.net/detail/BIM-463650

American Medical Association (AMA)

Reid, Antoinette M.& Brougham, Concepta A.& Fogarty, Andrew M.& Roche, James J.. Analysis of Bio-Obtainable Endocrine Disrupting Metals in River Water and Sediment, Sewage InfluentEffluent, Sludge, Leachate, and Concentrated Leachate, in the Irish Midlands Shannon Catchment. International Journal of Analytical Chemistry. 2010. Vol. 2009, no. 2009, pp.1-12.
https://search.emarefa.net/detail/BIM-463650

Data Type

Journal Articles

Language

English

Notes

Includes bibliographical references

Record ID

BIM-463650