Integrated Study of the Dinitrobenzene Electroreduction Mechanism by Electroanalytical and Computational Methods
Joint Authors
Syroeshkin, Mikhail A.
Gul'tyai, Vadim P.
Rusakov, Alexander I.
Mendkovich, Andrey S.
Mikhailov, Mikhail N.
Mikhalchenko, Ludmila V.
Source
International Journal of Electrochemistry
Issue
Vol. 2011, Issue 2011 (31 Dec. 2011), pp.1-12, 12 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2010-10-26
Country of Publication
Egypt
No. of Pages
12
Main Subjects
Abstract EN
Electroreduction of 1,2-, 1,3-, and 1,4-dinitrobenzenes in DMF has been investigated by a set of experimental (cyclic voltammetry, chronoamperometry, and controlled potential electrolysis) and theoretical methods (digital simulation and quantum chemical calculations).
The transformation of only one nitro group is observed in the presence of proton donors.
The process selectivity is provided by reactions of radical anions' intermediate products.
The key reactions here are protonation of radical anions of nitrosonitrobenzenes and N-O bond cleavage in radical anions of N-(nitrophenyl)-hydroxylamines.
American Psychological Association (APA)
Mendkovich, Andrey S.& Syroeshkin, Mikhail A.& Mikhalchenko, Ludmila V.& Mikhailov, Mikhail N.& Rusakov, Alexander I.& Gul'tyai, Vadim P.. 2010. Integrated Study of the Dinitrobenzene Electroreduction Mechanism by Electroanalytical and Computational Methods. International Journal of Electrochemistry،Vol. 2011, no. 2011, pp.1-12.
https://search.emarefa.net/detail/BIM-464523
Modern Language Association (MLA)
Mendkovich, Andrey S.…[et al.]. Integrated Study of the Dinitrobenzene Electroreduction Mechanism by Electroanalytical and Computational Methods. International Journal of Electrochemistry No. 2011 (2011), pp.1-12.
https://search.emarefa.net/detail/BIM-464523
American Medical Association (AMA)
Mendkovich, Andrey S.& Syroeshkin, Mikhail A.& Mikhalchenko, Ludmila V.& Mikhailov, Mikhail N.& Rusakov, Alexander I.& Gul'tyai, Vadim P.. Integrated Study of the Dinitrobenzene Electroreduction Mechanism by Electroanalytical and Computational Methods. International Journal of Electrochemistry. 2010. Vol. 2011, no. 2011, pp.1-12.
https://search.emarefa.net/detail/BIM-464523
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-464523