Synthesis and Structural Characterization of a Metal Cluster and a Coordination Polymer Based on the [Mn6(μ4-O)2]10+ Unit
Joint Authors
Tasiopoulos, Anastasios J.
Moushi, Eleni E.
Manos, Manolis J.
Source
Bioinorganic Chemistry and Applications
Issue
Vol. 2010, Issue 2010 (31 Dec. 2010), pp.1-7, 7 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2010-06-07
Country of Publication
Egypt
No. of Pages
7
Main Subjects
Abstract EN
A new 1-D coordination polymer {[Mn6O2(O2CMe)10(H2O)4]⋅2.5H2O}∞ (1⋅2.5H2O)∞ and the cluster [Mn6O2(O2(O2CPh)10 (py)2(MeCN)(H2O)]⋅2MeCN (2⋅2MeCN) are reported.
Both compounds were synthesized by room temperature reactions of [Mn3(μ3-O)(O2CR)6(L)2(L′)] (R = Me, L = L′ = py, (1⋅2.5H2O)∞; R = Ph, L = py, L′ = H2O, 2⋅2MeCN) in the presence of 3-hydroxymethylpyridine (3hmpH) in acetonitrile.
The structures of these complexes are based on hexanuclear mixed-valent manganese carboxylate clusters containing the [Mn4IIMn2III(μ4-O)2]10+ structural core.
(1⋅2.5H2O)∞ consists of zigzag chain polymers constructed from [Mn6O2(O2CMe)10(H2O)4] repeating units linked through acetate ligands, whereas 2⋅2MeCN comprises a discrete Mn6-benzoate cluster.
American Psychological Association (APA)
Moushi, Eleni E.& Tasiopoulos, Anastasios J.& Manos, Manolis J.. 2010. Synthesis and Structural Characterization of a Metal Cluster and a Coordination Polymer Based on the [Mn6(μ4-O)2]10+ Unit. Bioinorganic Chemistry and Applications،Vol. 2010, no. 2010, pp.1-7.
https://search.emarefa.net/detail/BIM-466319
Modern Language Association (MLA)
Moushi, Eleni E.…[et al.]. Synthesis and Structural Characterization of a Metal Cluster and a Coordination Polymer Based on the [Mn6(μ4-O)2]10+ Unit. Bioinorganic Chemistry and Applications No. 2010 (2010), pp.1-7.
https://search.emarefa.net/detail/BIM-466319
American Medical Association (AMA)
Moushi, Eleni E.& Tasiopoulos, Anastasios J.& Manos, Manolis J.. Synthesis and Structural Characterization of a Metal Cluster and a Coordination Polymer Based on the [Mn6(μ4-O)2]10+ Unit. Bioinorganic Chemistry and Applications. 2010. Vol. 2010, no. 2010, pp.1-7.
https://search.emarefa.net/detail/BIM-466319
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-466319
