Anion Effect of Zinc Source on Chemically Deposited ZnS(O,OH) Films
Joint Authors
Danilson, M.
Altosaar, M.
Varema, T.
Raudoja, J.
Ernits, K.
Volobujeva, O.
Muska, K.
Source
Advances in Materials Science and Engineering
Issue
Vol. 2009, Issue 2009 (31 Dec. 2009), pp.1-5, 5 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2010-02-09
Country of Publication
Egypt
No. of Pages
5
Main Subjects
Engineering Sciences and Information Technology
Abstract EN
The study on the anion effect of different Zn sources—Zn(CH3COO)2, ZnCl2, ZnI2, Zn(NO3)2 and ZnSO4—on the chemical deposition of ZnS(O,OH) films revealed that the growth rate and composition of the ZnS(O,OH) layer depend on the instability constant (pK) value of the corresponding Zn-complex Zn(L)n in the chemical bath solution.
In the region of pKZn(NH3)2+>pKZn(L)n the ZnS(O,OH) film's growth rate and ZnS concentration in films increased with the increasing pK value of the used Zn salt complex up to the pK value of the Zn[NH3]2+ complex and decreased in the region where pKZn(NH3)2+ The band gap values (around 3.6 eV in most cases) of deposited ZnS(O,OH) films did not depend on the Zn precursor's instability constant, the ZnS(O,OH) film from zinc nitrate containing bath has higher band gap energy (Eg = 3.8 eV). The maximum efficiency of CISSe and CZTSSe monograin layer solar cells was gained with ZnS(O,OH) buffer layer deposited from CBD solution containing Zn(CH3COO)2 as Zn source, which provided the highest growth rate and ZnS concentration in the ZnS(O,OH) film on glass substrates.
American Psychological Association (APA)
Ernits, K.& Muska, K.& Danilson, M.& Raudoja, J.& Varema, T.& Volobujeva, O.…[et al.]. 2010. Anion Effect of Zinc Source on Chemically Deposited ZnS(O,OH) Films. Advances in Materials Science and Engineering،Vol. 2009, no. 2009, pp.1-5.
https://search.emarefa.net/detail/BIM-466874
Modern Language Association (MLA)
Ernits, K.…[et al.]. Anion Effect of Zinc Source on Chemically Deposited ZnS(O,OH) Films. Advances in Materials Science and Engineering No. 2009 (2009), pp.1-5.
https://search.emarefa.net/detail/BIM-466874
American Medical Association (AMA)
Ernits, K.& Muska, K.& Danilson, M.& Raudoja, J.& Varema, T.& Volobujeva, O.…[et al.]. Anion Effect of Zinc Source on Chemically Deposited ZnS(O,OH) Films. Advances in Materials Science and Engineering. 2010. Vol. 2009, no. 2009, pp.1-5.
https://search.emarefa.net/detail/BIM-466874
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-466874