New Way to Substitute Tetracyanocyclopropanes : One-Pot Cascade Assembling of Carbonyls and Malononitrile by the Only Bromine Direct Action
Joint Authors
Vereshchagin, Anatolii N.
Stepanov, Nikita O.
Nikishin, Gennady I.
Elinson, Michail N.
Source
Issue
Vol. 2011, Issue 2011 (31 Dec. 2011), pp.1-5, 5 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2011-07-26
Country of Publication
Egypt
No. of Pages
5
Main Subjects
Abstract EN
The new type of the chemical cascade reaction was found: formation of cyclopropanes from carbonyl compounds and CH acid by the only bromine direct action.
The action of aqueous bromine on the carbonyl compounds and malononitrile in EtOH-H2O solutions in the presence of NaOAc results in the formation of 3-substituted 1,1,2,2-tetracyanocyclopropanes in 48–93% yields.
The latter are well-known precursors for the different bicyclic heterosystems, among them those containing cyclopropane ring and those possessing different types of pharmacological activity.
American Psychological Association (APA)
Vereshchagin, Anatolii N.& Elinson, Michail N.& Stepanov, Nikita O.& Nikishin, Gennady I.. 2011. New Way to Substitute Tetracyanocyclopropanes : One-Pot Cascade Assembling of Carbonyls and Malononitrile by the Only Bromine Direct Action. ISRN Organic Chemistry،Vol. 2011, no. 2011, pp.1-5.
https://search.emarefa.net/detail/BIM-473988
Modern Language Association (MLA)
Vereshchagin, Anatolii N.…[et al.]. New Way to Substitute Tetracyanocyclopropanes : One-Pot Cascade Assembling of Carbonyls and Malononitrile by the Only Bromine Direct Action. ISRN Organic Chemistry No. 2011 (2011), pp.1-5.
https://search.emarefa.net/detail/BIM-473988
American Medical Association (AMA)
Vereshchagin, Anatolii N.& Elinson, Michail N.& Stepanov, Nikita O.& Nikishin, Gennady I.. New Way to Substitute Tetracyanocyclopropanes : One-Pot Cascade Assembling of Carbonyls and Malononitrile by the Only Bromine Direct Action. ISRN Organic Chemistry. 2011. Vol. 2011, no. 2011, pp.1-5.
https://search.emarefa.net/detail/BIM-473988
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-473988
