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Separation of Functionalized 5,6-Disubstituted-1,10-Phenanthroline for Dye-Sensitized Solar Cell Applications
Joint Authors
Najafi, Leyla
Notash, Behrouz
Shahroosvand, Hashem
Abbasi, Parisa
Source
Issue
Vol. 2013, Issue 2013 (31 Dec. 2013), pp.1-8, 8 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2013-01-09
Country of Publication
Egypt
No. of Pages
8
Main Subjects
Abstract EN
5,6-Epoxy-1,10-phenanthroline is used as a convenient starting material for 5-hydroxy-6-Aryl-1,10-phenanthroline ligands containing carboxylic and sulfonic groups useful for further anchoring of the sensitizer on TiO2 for dye-sensitized solar cells (DSCs).
Based on the crystal growth of the mixture of products, a convenient separation route for the extension of the p-system on 5,6-disubstituted-1,10-phenanthroline was used to develop a novel series of functionalized 1,10-phenanthroline ligands with electron-withdrawing end-capping group.
Also, we report the epoxy opening of 5,6-epoxy-1,10-phenanthroline by aromatic amines stoichiometrically in refluxing water and ethanol in the absence of any catalyst.
The dyes were characterized by 1H-NMR, FT-IR, UV-Vis, and X-ray single crystal diffraction analyses.
It crystallizes in the monoclinic space group C 2/c, a = 20.920(4) Å, b = 10.340(2) Å, c = 16.187(3) Å, β = 92.30(3)°, V = 3498.6(12) Å3, and Z = 8.
The reaction details and features were described in detail.
American Psychological Association (APA)
Shahroosvand, Hashem& Abbasi, Parisa& Notash, Behrouz& Najafi, Leyla. 2013. Separation of Functionalized 5,6-Disubstituted-1,10-Phenanthroline for Dye-Sensitized Solar Cell Applications. Journal of Chemistry،Vol. 2013, no. 2013, pp.1-8.
https://search.emarefa.net/detail/BIM-474564
Modern Language Association (MLA)
Shahroosvand, Hashem…[et al.]. Separation of Functionalized 5,6-Disubstituted-1,10-Phenanthroline for Dye-Sensitized Solar Cell Applications. Journal of Chemistry No. 2013 (2013), pp.1-8.
https://search.emarefa.net/detail/BIM-474564
American Medical Association (AMA)
Shahroosvand, Hashem& Abbasi, Parisa& Notash, Behrouz& Najafi, Leyla. Separation of Functionalized 5,6-Disubstituted-1,10-Phenanthroline for Dye-Sensitized Solar Cell Applications. Journal of Chemistry. 2013. Vol. 2013, no. 2013, pp.1-8.
https://search.emarefa.net/detail/BIM-474564
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-474564