Development of a New Heterogeneous Lewis Acid Catalyst for Chemoselective Tetrahydropyranylation of Different Hydroxyl Compounds

Abstract EN

Amino functionalized triazine supported on silica-gel was prepared and characterized.

This new triazine derivative was applied as a coordinating agent for aluminum chloride.

This novel Lewis acid supported on heterogeneous surface was used as an effective catalyst for protection of alcohols and phenols in the presence of 3,4-dihydro-2H-pyran.

This catalyst can be reused without any significant loss of activity, and it protects alcohols in the presence of phenols.