Reversed-Phase Column Extractive Separation of Gd(III) with Poly[dibenzo-18-crown-6]
Joint Authors
Mohite, B. S.
Sabale, S. R.
Kadam, R. B.
Mahanwar, K. R.
Source
International Journal of Inorganic Chemistry
Issue
Vol. 2012, Issue 2012 (31 Dec. 2012), pp.1-6, 6 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2012-04-22
Country of Publication
Egypt
No. of Pages
6
Main Subjects
Abstract EN
A poly[dibenzo-18-crown-6] exhibits good chemical stability, reusability, and faster rate equilibrium for the separation of Gd(III).
Both uptake and stripping of metal ions were rapid, indicating a better accessibility of the complexing sites.
The proposed method has been applied for chromatographic separation of Gd(III) by using picric acid as medium and poly[dibenzo-18-crown-6] as stationary phase.
The influences of picric acid concentration, different eluting agents, and so forth, were discussed and the optimum conditions were established.
The breakthrough capacity of poly[dibenzo-18-crown-6] for Gd(III) was 0.572±0.01 mmolg-1 of crown polymer.
The proposed method has been applied to sequential chromatographic separation of their binary and multicomponent mixtures.
Gd(III) has been determined from real samples with good analytical reliability.
American Psychological Association (APA)
Mahanwar, K. R.& Sabale, S. R.& Kadam, R. B.& Mohite, B. S.. 2012. Reversed-Phase Column Extractive Separation of Gd(III) with Poly[dibenzo-18-crown-6]. International Journal of Inorganic Chemistry،Vol. 2012, no. 2012, pp.1-6.
https://search.emarefa.net/detail/BIM-477779
Modern Language Association (MLA)
Mahanwar, K. R.…[et al.]. Reversed-Phase Column Extractive Separation of Gd(III) with Poly[dibenzo-18-crown-6]. International Journal of Inorganic Chemistry No. 2012 (2012), pp.1-6.
https://search.emarefa.net/detail/BIM-477779
American Medical Association (AMA)
Mahanwar, K. R.& Sabale, S. R.& Kadam, R. B.& Mohite, B. S.. Reversed-Phase Column Extractive Separation of Gd(III) with Poly[dibenzo-18-crown-6]. International Journal of Inorganic Chemistry. 2012. Vol. 2012, no. 2012, pp.1-6.
https://search.emarefa.net/detail/BIM-477779
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-477779
