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Catalyst Initiation in the Oscillatory Carbonylation Reaction
Joint Authors
Parker, Julie
Novakovic, Katarina
Source
International Journal of Chemical Engineering
Issue
Vol. 2011, Issue 2011 (31 Dec. 2011), pp.1-11, 11 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2011-06-23
Country of Publication
Egypt
No. of Pages
11
Main Subjects
Engineering Sciences and Information Technology
Abstract EN
Palladium(II) iodide is used as a catalyst in the phenylacetylene oxidative carbonylation reaction that has demonstrated oscillatory behaviour in both pH and heat of reaction.
In an attempt to extract the reaction network responsible for the oscillatory nature of this reaction, the system was divided into smaller parts and they were studied.
This paper focuses on understanding the reaction network responsible for the initial reactions of palladium(II) iodide within this oscillatory reaction.
The species researched include methanol, palladium(II) iodide, potassium iodide, and carbon monoxide.
Several chemical reactions were considered and applied in a modelling study.
The study revealed the significant role played by traces of water contained in the standard HPLC grade methanol used.
American Psychological Association (APA)
Novakovic, Katarina& Parker, Julie. 2011. Catalyst Initiation in the Oscillatory Carbonylation Reaction. International Journal of Chemical Engineering،Vol. 2011, no. 2011, pp.1-11.
https://search.emarefa.net/detail/BIM-478095
Modern Language Association (MLA)
Novakovic, Katarina& Parker, Julie. Catalyst Initiation in the Oscillatory Carbonylation Reaction. International Journal of Chemical Engineering No. 2011 (2011), pp.1-11.
https://search.emarefa.net/detail/BIM-478095
American Medical Association (AMA)
Novakovic, Katarina& Parker, Julie. Catalyst Initiation in the Oscillatory Carbonylation Reaction. International Journal of Chemical Engineering. 2011. Vol. 2011, no. 2011, pp.1-11.
https://search.emarefa.net/detail/BIM-478095
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-478095