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Synthesis and Characterization of Novel Thiourea Derivatives and Their Nickel and Copper Complexes
Joint Authors
Binzet, Gün
Kavak, Gülten
Flörke, Ulrich
Arslan, Hakan
Özbey, Süheyla
Külcü, Nevzat
Source
Issue
Vol. 2013, Issue 2013 (31 Dec. 2013), pp.1-9, 9 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2013-09-03
Country of Publication
Egypt
No. of Pages
9
Main Subjects
Abstract EN
New benzoyl thiourea derivatives and their nickel and copper complexes were synthesized.
The structure of the synthesized compounds were confirmed by elemental analysis, FT-IR, and 1H NMR techniques.
Four of the synthesized compounds are analyzed by X-ray single crystal diffraction technique.
Whereas N,N-dimethyl-N′-(4-fluorobenzoyl)thiourea, N,N-diethyl-N′-(4-fluorobenzoyl)thiourea, and N,N-di-n-butyl-N′-(4-fluorobenzoyl) thiourea crystallize in the monoclinic system, bis(N,N-di-n-propyl-N′-(4-fluorobenzoyl)thioureato) nickel(II) complex crystallizes in the triclinic system.
These ligand molecules form dimers through strong intermolecular hydrogen bonds such as N–H⋯S, C–H⋯O, and N–H⋯O.
Moreover, there are different types of intramolecular interactions in the crystal structures.
Bis(N,N-dimethyl-N′-(4-fluorobenzoyl)thioureato) nickel(II) complex has a nearly square-planar coordination.
The distance of nickel atom from the best plane through the coordination sphere is 0.029 Å.
American Psychological Association (APA)
Binzet, Gün& Kavak, Gülten& Külcü, Nevzat& Özbey, Süheyla& Flörke, Ulrich& Arslan, Hakan. 2013. Synthesis and Characterization of Novel Thiourea Derivatives and Their Nickel and Copper Complexes. Journal of Chemistry،Vol. 2013, no. 2013, pp.1-9.
https://search.emarefa.net/detail/BIM-479542
Modern Language Association (MLA)
Binzet, Gün…[et al.]. Synthesis and Characterization of Novel Thiourea Derivatives and Their Nickel and Copper Complexes. Journal of Chemistry No. 2013 (2013), pp.1-9.
https://search.emarefa.net/detail/BIM-479542
American Medical Association (AMA)
Binzet, Gün& Kavak, Gülten& Külcü, Nevzat& Özbey, Süheyla& Flörke, Ulrich& Arslan, Hakan. Synthesis and Characterization of Novel Thiourea Derivatives and Their Nickel and Copper Complexes. Journal of Chemistry. 2013. Vol. 2013, no. 2013, pp.1-9.
https://search.emarefa.net/detail/BIM-479542
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-479542