Self-Assembly of Cluster-Based Nanoscopic Supramolecules into One-Dimensional Coordination Polymers
Joint Authors
Gamboa, Sergio Aarón
Zhang, Jian-Jun
Lachgar, Abdessadek
Davis, Barry Julian
Source
Advances in Materials Science and Engineering
Issue
Vol. 2009, Issue 2009 (31 Dec. 2009), pp.1-11, 11 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2009-10-19
Country of Publication
Egypt
No. of Pages
11
Main Subjects
Engineering Sciences and Information Technology
Abstract EN
Octahedral metal clusters [Nb6Cl12(CN)6]4−, (Mn(Salen))+ (or (Mn(7-MeSalen))+) (Salen = N,N′-ethylene-bis-(salicylidene)iminate) and ditopic organic linkers (4,4′-bpe (trans-1, 2-bis(4-pyridyl)-ethylene) or 4,4′-dpyo (4,4′-dipyridyl N,N′-dioxide)) self-assemble to form three cluster-based 1D coordination polymers: [Mn(Salen)(MeOH)2]2{(4,4′-dpyo) [(Mn(Salen))2(Nb6Cl12(CN)6)]}·2MeOH (1), {(4,4′-bpe)[(Mn(7-MeSalen))2(Mn(7-MeSalen)(H2O))2(Nb6Cl12(CN)6)]}·1.5MeCN·8H2O (2), and [(4,4′-bpe)(Mn(Salen)(H2O))2]{(4,4′-bpe)2[(Mn(Salen)(MeOH))2(Mn(Salen))2(Nb6Cl12(CN)6)][(Mn(Salen))2(Nb6Cl12(CN)6)]}·16H2O (3).
Single crystal X-ray diffraction analyses show that the frameworks of the three coordination polymers are built of heterotrimeric and/or heteropentameric supramolecular species linked by ditopic organic ligands.
The framework of 1 consists of anionic chains built of heterotrimeric dianions [(Mn(Salen))2(Nb6Cl12(CN)6)]2− (T) linked by 4,4′-dpyo.
The chains run along two directions ([0 2 −2] and [0 3 3]) leading to the formation of channels along the crystallographic (a) direction where the cations [Mn(Salen)(S)2]+ and solvent molecules are located.
Also, 2 was reported earlier, it possesses a neutral 1D chain built of neutral heterpentameric supramolecules: [(Mn(7‐MeSalen))2(Mn(7‐MeSalen)(S))2(Nb6Cl12(CN)6)] (P) linked by 4,4′-bpe ligands.
Hydrogen bonds between non-bridging cyanide ligands and coordinated solvent molecules connect the chains into 2D hydrogen-bonded frameworks.
Finally, 3 features an anionic chain, built of alternating heterotrimers [(Mn(Salen))2(Nb6Cl12(CN)6)]2− and heteropentamers [(Mn(Salen)(S))2(Mn(Salen))2(Nb6Cl12(CN)6)] linked by the organic spacer 4,4′-bpe.
The anionic charge is compensated by the in situe-assembled [Mn(Salen)(S)(4,4′‐bpe)Mn(Salen)(S)]2+ dimers.
Magnetic measurements reveal that the Mn(III) ions are well isolated and only weak magnetic interactions are observed.
The thermal stability of the three compounds was investigated.
American Psychological Association (APA)
Zhang, Jian-Jun& Gamboa, Sergio Aarón& Davis, Barry Julian& Lachgar, Abdessadek. 2009. Self-Assembly of Cluster-Based Nanoscopic Supramolecules into One-Dimensional Coordination Polymers. Advances in Materials Science and Engineering،Vol. 2009, no. 2009, pp.1-11.
https://search.emarefa.net/detail/BIM-482283
Modern Language Association (MLA)
Zhang, Jian-Jun…[et al.]. Self-Assembly of Cluster-Based Nanoscopic Supramolecules into One-Dimensional Coordination Polymers. Advances in Materials Science and Engineering No. 2009 (2009), pp.1-11.
https://search.emarefa.net/detail/BIM-482283
American Medical Association (AMA)
Zhang, Jian-Jun& Gamboa, Sergio Aarón& Davis, Barry Julian& Lachgar, Abdessadek. Self-Assembly of Cluster-Based Nanoscopic Supramolecules into One-Dimensional Coordination Polymers. Advances in Materials Science and Engineering. 2009. Vol. 2009, no. 2009, pp.1-11.
https://search.emarefa.net/detail/BIM-482283
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-482283