Synthesis and Structural Characterization of a New Tetranuclear Nickel(II) Sulfato Complex Containing the Anionic Form of Di-2-Pyridyl Ketone Oxime
Joint Authors
Moushi, Eleni E.
Efthymiou, Constantinos G.
Perlepes, Spyros P.
Source
International Journal of Inorganic Chemistry
Issue
Vol. 2011, Issue 2011 (31 Dec. 2011), pp.1-9, 9 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2011-04-20
Country of Publication
Egypt
No. of Pages
9
Main Subjects
Abstract EN
The preparation and crystal structure of a tetranuclear Ni(II) sulfato cluster containing the anion of di-2-pyridyl ketone oxime, (py)2CNO−, are reported.
Treatment of NiSO4⋅6H2O with one equivalent of (py)2CNOH and one equivalent of NEt3 in MeOH leads to the compound [Ni4{(py)2CNO}4(SO4)2(MeOH)4] (1) in moderate yield.
The metal ions are linked together by two 3.2111 and two 2.1110 (Harris notation) (py)2CNO− ligands, as well as two 2.1100 SO42− ions to create a rare metallacrown-type (12-MC-4) ring.
Strong H-bond intermolecular interactions in 1 lead to the formation of a 1D chain along the c axis.
Characteristic IR bands are discussed in terms of the known structure of 1.
American Psychological Association (APA)
Moushi, Eleni E.& Efthymiou, Constantinos G.& Perlepes, Spyros P.. 2011. Synthesis and Structural Characterization of a New Tetranuclear Nickel(II) Sulfato Complex Containing the Anionic Form of Di-2-Pyridyl Ketone Oxime. International Journal of Inorganic Chemistry،Vol. 2011, no. 2011, pp.1-9.
https://search.emarefa.net/detail/BIM-484552
Modern Language Association (MLA)
Moushi, Eleni E.…[et al.]. Synthesis and Structural Characterization of a New Tetranuclear Nickel(II) Sulfato Complex Containing the Anionic Form of Di-2-Pyridyl Ketone Oxime. International Journal of Inorganic Chemistry No. 2011 (2011), pp.1-9.
https://search.emarefa.net/detail/BIM-484552
American Medical Association (AMA)
Moushi, Eleni E.& Efthymiou, Constantinos G.& Perlepes, Spyros P.. Synthesis and Structural Characterization of a New Tetranuclear Nickel(II) Sulfato Complex Containing the Anionic Form of Di-2-Pyridyl Ketone Oxime. International Journal of Inorganic Chemistry. 2011. Vol. 2011, no. 2011, pp.1-9.
https://search.emarefa.net/detail/BIM-484552
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-484552