Synthesis, Crystal Structure, and DNA-Binding Studies of a Nickel(II) Complex with the Bis(2-benzimidazolymethyl)amine Ligand
Joint Authors
Kou, Fan
Yuan, Jingkun
Li, Ke
Bai, Ying
Liu, Bin
Sun, Tao
Wu, Huilu
Jia, Fei
Source
Bioinorganic Chemistry and Applications
Issue
Vol. 2012, Issue 2012 (31 Dec. 2012), pp.1-7, 7 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2011-08-18
Country of Publication
Egypt
No. of Pages
7
Main Subjects
Abstract EN
A V-shaped ligand Bis(2-benzimidazolymethyl)amine (bba) and its nickel(II) picrate (pic) complex, with composition [Ni(bba)2](pic)2⋅3MeOH, have been synthesized and characterized on the basis of elemental analyses, molar conductivities, IR spectra, and UV/vis measurements.
In the complex, the Ni(II) ion is six-coordinated with a N2O4 ligand set, resulting in a distorted octahedron coordination geometry.
In addition, the DNA-binding properties of the Ni(II) complex have been investigated by electronic absorption, fluorescence, and viscosity measurements.
The experimental results suggest that the nickel(II) complex binds to DNA by partial intercalation binding mode.
American Psychological Association (APA)
Wu, Huilu& Sun, Tao& Li, Ke& Liu, Bin& Kou, Fan& Jia, Fei…[et al.]. 2011. Synthesis, Crystal Structure, and DNA-Binding Studies of a Nickel(II) Complex with the Bis(2-benzimidazolymethyl)amine Ligand. Bioinorganic Chemistry and Applications،Vol. 2012, no. 2012, pp.1-7.
https://search.emarefa.net/detail/BIM-484890
Modern Language Association (MLA)
Wu, Huilu…[et al.]. Synthesis, Crystal Structure, and DNA-Binding Studies of a Nickel(II) Complex with the Bis(2-benzimidazolymethyl)amine Ligand. Bioinorganic Chemistry and Applications No. 2012 (2012), pp.1-7.
https://search.emarefa.net/detail/BIM-484890
American Medical Association (AMA)
Wu, Huilu& Sun, Tao& Li, Ke& Liu, Bin& Kou, Fan& Jia, Fei…[et al.]. Synthesis, Crystal Structure, and DNA-Binding Studies of a Nickel(II) Complex with the Bis(2-benzimidazolymethyl)amine Ligand. Bioinorganic Chemistry and Applications. 2011. Vol. 2012, no. 2012, pp.1-7.
https://search.emarefa.net/detail/BIM-484890
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-484890