Interactions of Trivalent Lanthanide Cations with a New Hexadentate Di-Schiff Base : New Lanthanide(III) Complexes from (NE,N′E)-2,2′-(ethane-1,2-diylbis(oxy))bis(N-(pyridin-2-ylmethylene)ethanamine)
Joint Authors
Skorda, Konstantina
Plakatouras, John C.
Papadimitriou, Christos
Tsiouri, Mantha
Li, Yang
Woollins, J. Derek
Source
Bioinorganic Chemistry and Applications
Issue
Vol. 2010, Issue 2010 (31 Dec. 2010), pp.1-7, 7 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2010-06-22
Country of Publication
Egypt
No. of Pages
7
Main Subjects
Abstract EN
The novel lanthanide(III) complexes [Ln(NO3)2L](NO3)⋅3MeOH (Ln = La 1, Pr 2) and [Ln(NO3)3L](NO3)⋅2MeOH (Ln = Gd 3, Yb 4), where L = (NE,N′E)-2,2′-(ethane-1,2-diylbis(oxy))bis(N-(pyridin-2-ylmethylene)ethanamine), have been obtained by direct reaction of the Schiff base ligand and the corresponding hydrated lanthanide(III) nitrates in methanol.
All complexes were characterized spectroscopically and thermogravimetrically.
Complex 4 was also characterized with crystallographic studies: orthorhombic P212121, a=10.6683(14), b=13.4752(15), c=19.3320(26) Å.
In the molecular structure of 4, Yb(III) is surrounded by all donor atoms of the Schiff base (four nitrogen and two oxygen atoms) and four oxygen atoms belonging to two bidentate chelating nitrato ligands.
American Psychological Association (APA)
Tsiouri, Mantha& Skorda, Konstantina& Papadimitriou, Christos& Li, Yang& Woollins, J. Derek& Plakatouras, John C.. 2010. Interactions of Trivalent Lanthanide Cations with a New Hexadentate Di-Schiff Base : New Lanthanide(III) Complexes from (NE,N′E)-2,2′-(ethane-1,2-diylbis(oxy))bis(N-(pyridin-2-ylmethylene)ethanamine). Bioinorganic Chemistry and Applications،Vol. 2010, no. 2010, pp.1-7.
https://search.emarefa.net/detail/BIM-485120
Modern Language Association (MLA)
Tsiouri, Mantha…[et al.]. Interactions of Trivalent Lanthanide Cations with a New Hexadentate Di-Schiff Base : New Lanthanide(III) Complexes from (NE,N′E)-2,2′-(ethane-1,2-diylbis(oxy))bis(N-(pyridin-2-ylmethylene)ethanamine). Bioinorganic Chemistry and Applications No. 2010 (2010), pp.1-7.
https://search.emarefa.net/detail/BIM-485120
American Medical Association (AMA)
Tsiouri, Mantha& Skorda, Konstantina& Papadimitriou, Christos& Li, Yang& Woollins, J. Derek& Plakatouras, John C.. Interactions of Trivalent Lanthanide Cations with a New Hexadentate Di-Schiff Base : New Lanthanide(III) Complexes from (NE,N′E)-2,2′-(ethane-1,2-diylbis(oxy))bis(N-(pyridin-2-ylmethylene)ethanamine). Bioinorganic Chemistry and Applications. 2010. Vol. 2010, no. 2010, pp.1-7.
https://search.emarefa.net/detail/BIM-485120
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-485120