First-Principles Study on Influences of Crystal Structure and Orientation on Band Offsets at the CdSCu2ZnSnS4 Interface
Joint Authors
Ichimura, Masaya
Bao, Wujisiguleng
Source
International Journal of Photoenergy
Issue
Vol. 2012, Issue 2012 (31 Dec. 2012), pp.1-5, 5 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2012-12-03
Country of Publication
Egypt
No. of Pages
5
Main Subjects
Abstract EN
Cu2ZnSnS4 (CZTS) has attracted much attention recently as an absorber layer material in a heterojunction solar cell.
Using the first-principles method, we calculate the band offsets for the CdS/CZTS heterojunction.
The valence band offset ΔEv is 1.2 eV for the (001) CdS/CZTS heterointerface and 1.0 eV for the (010) heterointerface, when CZTS is considered to crystallize in the kesterite structure.
When CZTS is considered to crystallize in the stannite structure, ΔEv=1.1 eV for the (001) heterointerface and ΔEv=1.3 eV for the (010) heterointerface.
In any case, the conduction band minimum of CZTS is higher than that of CdS, and the conduction band offset ΔEc is in a range between 0.1 and 0.4 eV.
American Psychological Association (APA)
Bao, Wujisiguleng& Ichimura, Masaya. 2012. First-Principles Study on Influences of Crystal Structure and Orientation on Band Offsets at the CdSCu2ZnSnS4 Interface. International Journal of Photoenergy،Vol. 2012, no. 2012, pp.1-5.
https://search.emarefa.net/detail/BIM-485717
Modern Language Association (MLA)
Bao, Wujisiguleng& Ichimura, Masaya. First-Principles Study on Influences of Crystal Structure and Orientation on Band Offsets at the CdSCu2ZnSnS4 Interface. International Journal of Photoenergy No. 2012 (2012), pp.1-5.
https://search.emarefa.net/detail/BIM-485717
American Medical Association (AMA)
Bao, Wujisiguleng& Ichimura, Masaya. First-Principles Study on Influences of Crystal Structure and Orientation on Band Offsets at the CdSCu2ZnSnS4 Interface. International Journal of Photoenergy. 2012. Vol. 2012, no. 2012, pp.1-5.
https://search.emarefa.net/detail/BIM-485717
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-485717