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Preparation of Organic-Inorganic Hybrid Materials Based on MCM-41 and Its Applications
Joint Authors
Mohamad, Sharifah
Jamil Maah, Mohd
Alahmadi, Sana M.
Source
Advances in Materials Science and Engineering
Issue
Vol. 2013, Issue 2013 (31 Dec. 2013), pp.1-8, 8 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2013-11-20
Country of Publication
Egypt
No. of Pages
8
Main Subjects
Engineering Sciences and Information Technology
Abstract EN
This work reports the covalent attachment of three different calix[4]arenes (calix[4]arene (C4), p-sulfonatocalix[4]arene (C4S), and p-tert-butyl-calix[4]arene (PC4)) to MCM-41, using a three-step modification process.
3-Chloropropyltrimethoxysilane (ClPTS) was first attached to the mesoporous silica surface and subsequently converted to amides via the reaction with toluene diisocyanate (TDI).
Finally, calix[4]arene derivatives attached to the isocyanate ending remained available on toluene di-iso-cyanate.
Changes in the surface properties of the mesoporous silica caused by the chemical modification were monitored using the Fourier transform infrared spectroscopy (FTIR), thermal analysis (TGA), and elemental analysis.
The FTIR spectra and TGA analysis verify that the calix[4]arene derivatives are covalently attached to the mesoporous silica.
The preservation of the MCM-41 channel system was checked by the X-ray diffraction and nitrogen adsorption analysis.
These materials were then used to evaluate the sorption properties of some organotins compounds (Tributyltin (TBT), Triphenyltin (TPT), and Dibutyltin (DBT)).
American Psychological Association (APA)
Alahmadi, Sana M.& Mohamad, Sharifah& Jamil Maah, Mohd. 2013. Preparation of Organic-Inorganic Hybrid Materials Based on MCM-41 and Its Applications. Advances in Materials Science and Engineering،Vol. 2013, no. 2013, pp.1-8.
https://search.emarefa.net/detail/BIM-486895
Modern Language Association (MLA)
Alahmadi, Sana M.…[et al.]. Preparation of Organic-Inorganic Hybrid Materials Based on MCM-41 and Its Applications. Advances in Materials Science and Engineering No. 2013 (2013), pp.1-8.
https://search.emarefa.net/detail/BIM-486895
American Medical Association (AMA)
Alahmadi, Sana M.& Mohamad, Sharifah& Jamil Maah, Mohd. Preparation of Organic-Inorganic Hybrid Materials Based on MCM-41 and Its Applications. Advances in Materials Science and Engineering. 2013. Vol. 2013, no. 2013, pp.1-8.
https://search.emarefa.net/detail/BIM-486895
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-486895