Computation of Isobaric Vapor-Liquid Equilibrium Data for Binary and Ternary Mixtures of Methanol, Water, and Ethanoic Acid from T, p, x, and HmE Measurements
Joint Authors
Sun, Hong
Chen, Hong
Zhu, Dechun
Gao, Daming
Shi, Jianjun
Si, Jingyu
Zhang, Hui
Lücking, Peter
Source
Issue
Vol. 2012, Issue 2012 (31 Dec. 2012), pp.1-13, 13 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2012-10-10
Country of Publication
Egypt
No. of Pages
13
Main Subjects
Abstract EN
Vapor-liquid equilibrium (VLE) data for the strongly associated ternary system methanol + water + ethanoic acid and the three constituent binary systems have been determined by the total pressure-temperature-liquid-phase composition-molar excess enthalpy of mixing of the liquid phase (p, T, x, HmE) for the binary systems using a novel pump ebulliometer at 101.325 kPa.
The vapor-phase compositions of these binary systems had been calculated from Tpx and HmE based on the Q function of molar excess Gibbs energy through an indirect method.
Moreover, the experimental T, x data are used to estimate nonrandom two-liquid (NRTL), Wilson, Margules, and van Laar model parameters, and these parameters in turn are used to calculate vapor-phase compositions.
The activity coefficients of the solution were correlated with NRTL, Wilson, Margules, and van Laar models through fitting by least-squares method.
The VLE data of the ternary system were well predicted from these binary interaction parameters of NRTL, Wilson, Margules, and van Laar model parameters without any additional adjustment to build the thermodynamic model of VLE for the ternary system and obtain the vapor-phase compositions and the calculated bubble points.
American Psychological Association (APA)
Gao, Daming& Zhang, Hui& Lücking, Peter& Sun, Hong& Si, Jingyu& Zhu, Dechun…[et al.]. 2012. Computation of Isobaric Vapor-Liquid Equilibrium Data for Binary and Ternary Mixtures of Methanol, Water, and Ethanoic Acid from T, p, x, and HmE Measurements. Journal of Thermodynamics،Vol. 2012, no. 2012, pp.1-13.
https://search.emarefa.net/detail/BIM-487498
Modern Language Association (MLA)
Gao, Daming…[et al.]. Computation of Isobaric Vapor-Liquid Equilibrium Data for Binary and Ternary Mixtures of Methanol, Water, and Ethanoic Acid from T, p, x, and HmE Measurements. Journal of Thermodynamics No. 2012 (2012), pp.1-13.
https://search.emarefa.net/detail/BIM-487498
American Medical Association (AMA)
Gao, Daming& Zhang, Hui& Lücking, Peter& Sun, Hong& Si, Jingyu& Zhu, Dechun…[et al.]. Computation of Isobaric Vapor-Liquid Equilibrium Data for Binary and Ternary Mixtures of Methanol, Water, and Ethanoic Acid from T, p, x, and HmE Measurements. Journal of Thermodynamics. 2012. Vol. 2012, no. 2012, pp.1-13.
https://search.emarefa.net/detail/BIM-487498
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-487498