Synthesis, Characterization, and Magnetic and Thermal Studies on Some Metal(II)‎ Thiophenyl Schiff Base Complexes

Abstract EN

4-(Thiophen-3-yl)-aniline undergoes condensation with o-vanillin to form an ONS donor Schiff base, 2-methoxy-6-[(4-thiophene-3-yl-phenylimino)-methyl]-phenol, which forms complexes of the type [ML2]xH2O (where M = Mn, Co, Ni, Cu, Zn, Pd).

These complexes are characterized by elemental analysis, 1H nmr, electronic, mass, and IR spectroscopies and conductance measurements.

The electronic, IR and CHN data are supportive of a 4-coordinate tetrahedral geometry for Mn(II), Co(II), Ni(II), and Zn(II) complexes and square-planar geometry for Cu(II) and Pd(II) complexes, with the chromophores N2O2.

The magnetic data reveals that the complexes are magnetically dilute and mononuclear with exception of the Cu(II) complex, which exhibits some anti-ferromagnetisms.

The complexes are air-stable solids, and none is an electrolyte in nitro methane.