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Synthesis, Crystal Structure, and Characterization of a New Organic-Inorganic Hybrid Material : H3AEP2·BiCl6·3Cl·2H2O
Joint Authors
Ferjani, Hela
Driss, Ahmed
Boughzala, Habib
Source
Issue
Vol. 2013, Issue 2013 (31 Dec. 2013), pp.1-8, 8 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2013-07-11
Country of Publication
Egypt
No. of Pages
8
Main Subjects
Abstract EN
The title compound is an organic-inorganic hybrid material.
The single crystal X-ray diffraction investigation reveals that the studied compound crystallizes in the orthorhombic system, space group Pbca with the following lattice parameters: a=12.108 (4) Å, b=19.403 (3) Å, c=24.933 (6) Å, and Z=8.
The crystal lattice is composed of a discrete (BiCl6)3- anion surrounded by piperazinium cations, chlorine anions, and water molecules.
Complex hydrogen bonding interactions between (BiCl6)3-, Cl−, organic cations, and water molecules form a three-dimensional network.
Room temperature IR, Raman spectroscopy, and optical absorption of the title compound were recorded and analysed.
The observed crystal morphology was compared to the simulated one using the Bravais-Friedel, Donnay-Harker model.
American Psychological Association (APA)
Ferjani, Hela& Boughzala, Habib& Driss, Ahmed. 2013. Synthesis, Crystal Structure, and Characterization of a New Organic-Inorganic Hybrid Material : H3AEP2·BiCl6·3Cl·2H2O. Journal of Crystallography،Vol. 2013, no. 2013, pp.1-8.
https://search.emarefa.net/detail/BIM-488948
Modern Language Association (MLA)
Ferjani, Hela…[et al.]. Synthesis, Crystal Structure, and Characterization of a New Organic-Inorganic Hybrid Material : H3AEP2·BiCl6·3Cl·2H2O. Journal of Crystallography No. 2013 (2013), pp.1-8.
https://search.emarefa.net/detail/BIM-488948
American Medical Association (AMA)
Ferjani, Hela& Boughzala, Habib& Driss, Ahmed. Synthesis, Crystal Structure, and Characterization of a New Organic-Inorganic Hybrid Material : H3AEP2·BiCl6·3Cl·2H2O. Journal of Crystallography. 2013. Vol. 2013, no. 2013, pp.1-8.
https://search.emarefa.net/detail/BIM-488948
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-488948