Deuterium Isotope Effects on N14,15 Chemical Shifts of Ammonium Ions : A Solid State NMR Study

Author

Hansen, Poul Erik

Source

International Journal of Inorganic Chemistry

Issue

Vol. 2011, Issue 2011 (31 Dec. 2011), pp.1-4, 4 p.

Publisher

Hindawi Publishing Corporation

Publication Date

2011-12-27

Country of Publication

Egypt

No. of Pages

4

Main Subjects

Chemistry

Abstract EN

Deuterium isotope effects on N14,15 chemical shifts are measured in ammonium halides in the solid state using both enriched N15 salts and N14 natural abundance materials.

The effects are correlated to N15 chemical shifts and to N···X distances.

The deuterium isotope effects on N14,15 chemical shifts in the solid state are discussed in relation to effects observed in solution.

No NH couplings are seen due to fast rotation in the solid, which leads to self-decoupling, whereas ND couplings are present.

American Psychological Association (APA)

Hansen, Poul Erik. 2011. Deuterium Isotope Effects on N14,15 Chemical Shifts of Ammonium Ions : A Solid State NMR Study. International Journal of Inorganic Chemistry،Vol. 2011, no. 2011, pp.1-4.
https://search.emarefa.net/detail/BIM-491366

Modern Language Association (MLA)

Hansen, Poul Erik. Deuterium Isotope Effects on N14,15 Chemical Shifts of Ammonium Ions : A Solid State NMR Study. International Journal of Inorganic Chemistry No. 2011 (2011), pp.1-4.
https://search.emarefa.net/detail/BIM-491366

American Medical Association (AMA)

Hansen, Poul Erik. Deuterium Isotope Effects on N14,15 Chemical Shifts of Ammonium Ions : A Solid State NMR Study. International Journal of Inorganic Chemistry. 2011. Vol. 2011, no. 2011, pp.1-4.
https://search.emarefa.net/detail/BIM-491366

Data Type

Journal Articles

Language

English

Notes

Includes bibliographical references

Record ID

BIM-491366