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Polyethylene Glycol Mediated Kinetic Study of Nitro Decarboxylation of α,β-Unsaturated Acids by Blau’s Fe(III) Phen Complex
Joint Authors
Saiprakash, P. K.
Shylaja, S.
Giridhar Reddy, P.
Ramesh, K.
Rajanna, K. C.
Source
Issue
Vol. 2013, Issue 2013 (31 Dec. 2013), pp.1-10, 10 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2013-10-10
Country of Publication
Egypt
No. of Pages
10
Main Subjects
Abstract EN
Polyethylene glycol (PEG) mediated kinetic study of nitro decarboxylation of α,β-unsaturated acids (USA) has been taken up by Blau’s [Fe(III) nitrate-Phen] yellow complex in acetonitrile medium.
Kinetics of the reactions indicated Michaelis-Menton type of mechanism and rate law.
Reaction rates are significantly influenced by the structural variation and concentration of PEG.
Catalysis of PEG was explained on the lines of nonionic micelles such as TX-100 because of their structural resemblance and also due to a slight negative charge developed on polyoxyethylene and cationic form(s) of Fe(III) chelates in the intermediate stages.
American Psychological Association (APA)
Ramesh, K.& Shylaja, S.& Rajanna, K. C.& Giridhar Reddy, P.& Saiprakash, P. K.. 2013. Polyethylene Glycol Mediated Kinetic Study of Nitro Decarboxylation of α,β-Unsaturated Acids by Blau’s Fe(III) Phen Complex. Journal of Chemistry،Vol. 2013, no. 2013, pp.1-10.
https://search.emarefa.net/detail/BIM-491813
Modern Language Association (MLA)
Ramesh, K.…[et al.]. Polyethylene Glycol Mediated Kinetic Study of Nitro Decarboxylation of α,β-Unsaturated Acids by Blau’s Fe(III) Phen Complex. Journal of Chemistry No. 2013 (2013), pp.1-10.
https://search.emarefa.net/detail/BIM-491813
American Medical Association (AMA)
Ramesh, K.& Shylaja, S.& Rajanna, K. C.& Giridhar Reddy, P.& Saiprakash, P. K.. Polyethylene Glycol Mediated Kinetic Study of Nitro Decarboxylation of α,β-Unsaturated Acids by Blau’s Fe(III) Phen Complex. Journal of Chemistry. 2013. Vol. 2013, no. 2013, pp.1-10.
https://search.emarefa.net/detail/BIM-491813
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-491813