Synthesis, Crystal Structure, and Spectra Properties of the Cadmium (II) Complex with Bis(N-allylbenzimidazol-2-ylmethyl)benzylamine
Joint Authors
Kou, Fan
Yuan, Jingkun
Bai, Ying
Liu, Bin
Wu, Huilu
Jia, Fei
Source
Bioinorganic Chemistry and Applications
Issue
Vol. 2011, Issue 2011 (31 Dec. 2011), pp.1-9, 9 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2011-10-05
Country of Publication
Egypt
No. of Pages
9
Main Subjects
Abstract EN
A novel complex of cadmium (II) picrate (pic) with V-shaped ligand bis(N-allylbenzimidazol-2-ylmethyl)benzylamine (babb), with composition [Cd(babb)2](pic)2, was synthesized and characterized by elemental analyses and electrical conductivity, IR, and UV/visible spectra.
The crystal structure of the complex has been determined by the single-crystal X-ray diffraction.
In the complex, the coordination sphere around Cd (II) is distorted octahedral, six nitrogen atoms involved in coordination afforded by two tridentate ligand babb.
Moreover, The DNA-binding properties of the ligand babb and Cd (II) complex were investigated by spectrophotometric methods and viscosity measurements, and the results suggest that they bind to DNA via an intercalation binding mode, and the Cd (II) complex shows higher affinity than the ligand.
American Psychological Association (APA)
Wu, Huilu& Yuan, Jingkun& Bai, Ying& Kou, Fan& Jia, Fei& Liu, Bin. 2011. Synthesis, Crystal Structure, and Spectra Properties of the Cadmium (II) Complex with Bis(N-allylbenzimidazol-2-ylmethyl)benzylamine. Bioinorganic Chemistry and Applications،Vol. 2011, no. 2011, pp.1-9.
https://search.emarefa.net/detail/BIM-492057
Modern Language Association (MLA)
Wu, Huilu…[et al.]. Synthesis, Crystal Structure, and Spectra Properties of the Cadmium (II) Complex with Bis(N-allylbenzimidazol-2-ylmethyl)benzylamine. Bioinorganic Chemistry and Applications No. 2011 (2011), pp.1-9.
https://search.emarefa.net/detail/BIM-492057
American Medical Association (AMA)
Wu, Huilu& Yuan, Jingkun& Bai, Ying& Kou, Fan& Jia, Fei& Liu, Bin. Synthesis, Crystal Structure, and Spectra Properties of the Cadmium (II) Complex with Bis(N-allylbenzimidazol-2-ylmethyl)benzylamine. Bioinorganic Chemistry and Applications. 2011. Vol. 2011, no. 2011, pp.1-9.
https://search.emarefa.net/detail/BIM-492057
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-492057