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Synthesis, Characterization, and Crystal Structure of a Diorganotin(IV) Complex with 2-Oxo-2-Phenylacetic Acid 4-Hydroxybenzohydrazone
Joint Authors
Source
Issue
Vol. 2011, Issue 2011 (31 Dec. 2011), pp.1-5, 5 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2011-04-11
Country of Publication
Egypt
No. of Pages
5
Main Subjects
Abstract EN
The complex dibutyltin 2-oxo-2-phenylacetic acid 4-hydroxybenzohydrazone has been synthesized and characterized by elemental analysis, IR, 1H and 13C NMR, and X-ray single-crystal diffraction studies.
The crystal structure belongs to triclinic, space group P-1 with a=9.3220 (10) Å, b=9.8779 (11) Å, c=15.9401 (17) Å, β=97.0930 (10)∘, Z=2, V=1427.6(3) Å3, Dc=1.413 mg/cm3, μ=0.936 mm−1, F(000)=628, R=0.1158, and wR=0.2522.
X-ray analysis indicates that O(2), N(2), O(4), and O(4)#1 from the ligand and O(5) from ethanol molecule are in the equatorial positions; the axial positions are occupied by two n-butyl groups.
It shows a distorted pentagonal bipyramid configuration with seven-coordination for central tin atom.
Fascinatingly, the supramolecular infrastructures are observed, which exist as two-dimensional sheets assembled from the organometallic subunits through intermolecular and intramolecular O–H⋯X or C–H⋯X (X = O or N) hydrogen bonds.
American Psychological Association (APA)
Li, Jing& Yin, Handong& Hong, Min. 2011. Synthesis, Characterization, and Crystal Structure of a Diorganotin(IV) Complex with 2-Oxo-2-Phenylacetic Acid 4-Hydroxybenzohydrazone. ISRN Organic Chemistry،Vol. 2011, no. 2011, pp.1-5.
https://search.emarefa.net/detail/BIM-492225
Modern Language Association (MLA)
Li, Jing…[et al.]. Synthesis, Characterization, and Crystal Structure of a Diorganotin(IV) Complex with 2-Oxo-2-Phenylacetic Acid 4-Hydroxybenzohydrazone. ISRN Organic Chemistry No. 2011 (2011), pp.1-5.
https://search.emarefa.net/detail/BIM-492225
American Medical Association (AMA)
Li, Jing& Yin, Handong& Hong, Min. Synthesis, Characterization, and Crystal Structure of a Diorganotin(IV) Complex with 2-Oxo-2-Phenylacetic Acid 4-Hydroxybenzohydrazone. ISRN Organic Chemistry. 2011. Vol. 2011, no. 2011, pp.1-5.
https://search.emarefa.net/detail/BIM-492225
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-492225