Copper Nanoparticles Prepared from Oxalic Precursors

Abstract EN

The synthesis of nanoparticles of copper metal via a soft chemistry route is presented in this paper.

The method is based on the thermal decomposition under nitrogen or hydrogen of oxalic precursors with a well-controlled morphology and particle size.

The precipitation of the copper oxalates in a water-alcohol medium allows the submicron size of the precursor grains to be controlled and, consequently, the nanometric size of the metallic copper particles to be determined, as required, between 3.5 and 40 nm.

The majority of the final particles are made of pure copper metal although some present a superficial layer of cuprous oxide (Cu2O).