Methane Activation and Transformation on Polyoxometalates
Joint Authors
Putaj, Piotr
Grinenval, Eva
Lefebvre, Frédéric
Source
Issue
Vol. 2013, Issue 2013 (31 Dec. 2013), pp.1-9, 9 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2013-01-14
Country of Publication
Egypt
No. of Pages
9
Main Subjects
Engineering Sciences and Information Technology
Chemistry
Abstract EN
Methane is activated at moderate temperature on polyoxometalates, leading to the evolution of hydrogen and the formation of a methoxy species which has been characterized by solid-state C13 CP-MAS NMR.
In the case of a molybdic polyoxometalate, the methyl group is linked to an edge-shared oxygen atom of the polyoxometalate.
Upon heating, it reacts with oxygens of the polyoxometalate resulting in the formation of formyl species and then carbon dioxide and a reduction of molybdenum.
Upon treatment with water, only traces of methanol can be detected.
American Psychological Association (APA)
Lefebvre, Frédéric& Grinenval, Eva& Putaj, Piotr. 2013. Methane Activation and Transformation on Polyoxometalates. Journal of Catalysts،Vol. 2013, no. 2013, pp.1-9.
https://search.emarefa.net/detail/BIM-494171
Modern Language Association (MLA)
Lefebvre, Frédéric…[et al.]. Methane Activation and Transformation on Polyoxometalates. Journal of Catalysts No. 2013 (2013), pp.1-9.
https://search.emarefa.net/detail/BIM-494171
American Medical Association (AMA)
Lefebvre, Frédéric& Grinenval, Eva& Putaj, Piotr. Methane Activation and Transformation on Polyoxometalates. Journal of Catalysts. 2013. Vol. 2013, no. 2013, pp.1-9.
https://search.emarefa.net/detail/BIM-494171
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-494171
