Kinetics and Mechanism of Oxidation of Leucine and Alanine by Ag(III) Complex in Alkaline Medium
Joint Authors
Shan, Jin-huan
Song, Changying
Chen, Lei
Source
Research Letters in Inorganic Chemistry
Issue
Vol. 2008, Issue 2008 (31 Dec. 2008), pp.1-4, 4 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2008-10-14
Country of Publication
Egypt
No. of Pages
4
Main Subjects
Abstract EN
Kinetics and mechanism of oxidation of leucine and alanine by Ag(III) complex were studied spectrophotometrically in alkaline medium at constant ion strength.
The reaction was in first order with respect to Ag(III) complex and amino acids (leucine, alanine).
The second-order rate constant, k−, decreased with the increasing in [OH−] and [IO4−].
A plausible mechanism was proposed from the kinetics study, and the rate equations derived from mechanism can explain all experimental phenomena.
The activation parameters were calculated at 298.2 K.
American Psychological Association (APA)
Song, Changying& Chen, Lei& Shan, Jin-huan. 2008. Kinetics and Mechanism of Oxidation of Leucine and Alanine by Ag(III) Complex in Alkaline Medium. Research Letters in Inorganic Chemistry،Vol. 2008, no. 2008, pp.1-4.
https://search.emarefa.net/detail/BIM-498047
Modern Language Association (MLA)
Song, Changying…[et al.]. Kinetics and Mechanism of Oxidation of Leucine and Alanine by Ag(III) Complex in Alkaline Medium. Research Letters in Inorganic Chemistry No. 2008 (2008), pp.1-4.
https://search.emarefa.net/detail/BIM-498047
American Medical Association (AMA)
Song, Changying& Chen, Lei& Shan, Jin-huan. Kinetics and Mechanism of Oxidation of Leucine and Alanine by Ag(III) Complex in Alkaline Medium. Research Letters in Inorganic Chemistry. 2008. Vol. 2008, no. 2008, pp.1-4.
https://search.emarefa.net/detail/BIM-498047
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-498047
